Silicon-stereogenic chiral organosilanes have found increasing applications in synthetic
chemistry, medicinal chemistry, and materials science. In this context, various asymmetric …

Conspectus The development of highly effective chiral ligands is a key topic in enhancing
the catalytic activity and selectivity in metal-catalyzed asymmetric synthesis. Traditionally …

Silicon-stereogenic organosilanes have attracted heightened attention in various scientific
communities including synthetic chemistry, material chemistry, and medicinal chemistry …

Isomerization-based strategies to enable the stereodivergent construction of complex
polyenes from geometrically defined alkene linchpins remain conspicuously …

Despite impressive advances in the construction of enantioenriched silacarbocycles
featuring silicon‐stereogenic centers via a selection of well‐defined sila‐synthons, the …

A rhodium-catalyzed tandem enantioselective C–H silylation/alkene hydrosilylation of
dihydrosilanes, which enables the streamlined construction of a wide range of silicon …

Despite the growing demand for the enantioenriched silicon-stereogenic silanols in
materials science, medicinal chemistry, and modern synthetic chemistry, the catalytic …

Chiral monophosphorus ligands are playing an important role for the recent advances in
asymmetric catalysis. This review summarizes the latest progress in various asymmetric …

Enantiopure monohydrosilanes are versatile chiral reagents for alcohol resolution and
mechanistic investigation. Herein, we have demonstrated the asymmetric synthesis of …

The strategic carbon‐to‐silicon substitution at a stereogenic center can produce chiral
silanes with significantly improved properties relative to their carbon congeners. We herein …