The structural complexity of glycans poses a serious challenge in the chemical synthesis of
glycosides, oligosaccharides and glycoconjugates. Glycan complexity, determined by …

Catalytic glycosylation has been a central reaction in carbohydrate chemistry since its
introduction by Fischer 125 years ago, but it is only in the past three to four decades that …

Recent developments in stereoselective 1, 2-cis glycosylation that have emerged during the
past decade are surveyed herein. For detailed coverage of the previous achievements in the …

The translation of biological glycosylation in humans to the clinical applications involves
systematic studies using homogeneous samples of oligosaccharides and glycoconjugates …

With easily accessible and operator-friendly reagents, shelf-stable ortho-
methoxycarbonylethynylphenyl thioglycosides were efficiently prepared. Based on these …

The efficient synthesis of long, branched, and complex carbohydrates containing multiple 1,
2‐cis glycosidic linkages is a long‐standing challenge. Here, we report a merging reagent …

The stereoselective formation of 1, 2-cis-glycosidic bonds is a major bottleneck in the
synthesis of carbohydrates. We here investigate how the electron density in acyl protecting …

Saccharides are polyhydroxy compounds, and their synthesis requires complex protecting
group manipulations. Protecting groups are usually used to temporarily mask a functional …

Acinetobacter baumannii is a opportunistic bacterial pathogen responsible for serious
nosocomial infections that is becoming increasingly resistant against antibiotics. Capsular …

The key steps in oligosaccharide synthesis are protectinggroup manipulation and
stereoselective glycosylation.[1] Various strategies have emerged to expedite glycosylation …