Multiscale studies on ionic liquids

K Dong, X Liu, H Dong, X Zhang, S Zhang - Chemical reviews, 2017 - ACS Publications
Ionic liquids (ILs) offer a wide range of promising applications because of their much
enhanced properties. However, further development of such materials depends on the …

Phase variety in ionic liquids: Hydrogen bonding and molecular conformations

H Abe - Journal of Molecular Liquids, 2021 - Elsevier
Ionic liquids (ILs) have a phase variety due to degrees of freedom of hydrogen bonding and
molecular conformations. Liquid, amorphous, and crystal phases of the ILs and their …

Additive engineering enables ionic-liquid electrolyte-based supercapacitors to deliver simultaneously high energy and power density

X Jiang, X Wu, Y **e, Z Wang, J Huang… - ACS Sustainable …, 2023 - ACS Publications
Ionic liquid (IL) electrolytes with a high potential window are promising candidates to high-
energy-density supercapacitors; however, they commonly suffer from serious kinetic barriers …

Solvation dynamics in ionic liquids: what we have learned from the dynamic fluorescence stokes shift studies

A Samanta - The Journal of Physical Chemistry Letters, 2010 - ACS Publications
Ionic liquids have generated tremendous excitement as a new class of solvent systems
having the potential to serve as an environmentally friendly alternative to the traditionally …

[HTML][HTML] Temperature-transferable coarse-graining of ionic liquids with dual graph convolutional neural networks

J Ruza, W Wang, D Schwalbe-Koda… - The Journal of …, 2020 - pubs.aip.org
Computer simulations can provide mechanistic insight into ionic liquids (ILs) and predict the
properties of experimentally unrealized ion combinations. However, ILs suffer from a …

Complete solvation response of coumarin 153 in ionic liquids

XX Zhang, M Liang, NP Ernsting… - The Journal of Physical …, 2013 - ACS Publications
The dynamic Stokes shift of coumarin 153, measured with a combination of broad-band
fluorescence upconversion (80 fs resolution) and time-correlated single photon counting (to …

Interaction and dynamics of (alkylamide+ electrolyte) deep eutectics: Dependence on alkyl chain-length, temperature, and anion identity

B Guchhait, S Das, S Daschakraborty… - The Journal of Chemical …, 2014 - pubs.aip.org
Here we investigate the solute-medium interaction and solute-centered dynamics in
(RCONH 2+ LiX) deep eutectics (DEs) via carrying out time-resolved fluorescence …

Ion–molecule complex dissociation and formation dynamics in LiCl aqueous solutions from 2D IR spectroscopy

R Yuan, C Yan, M Fayer - The Journal of Physical Chemistry B, 2018 - ACS Publications
Ion–molecule complex dynamics as well as water dynamics in concentrated lithium chloride
(LiCl) solutions are examined using ultrafast two-dimensional infrared (2D IR) spectroscopy …

Medium decoupling of dynamics at temperatures∼ 100 K above glass-transition temperature: A case study with (acetamide+ lithium bromide/nitrate) melts

B Guchhait, S Daschakraborty, R Biswas - The Journal of Chemical …, 2012 - pubs.aip.org
Time-resolved fluorescence Stokes shift and anisotropy measurements using a solvation
probe in [0.78 CH 3 CONH 2+ 0.22 {f LiBr+(1-f) LiNO 3}] melts reveal a strong decoupling of …

How does addition of lithium salt influence the structure and dynamics of choline chloride-based deep eutectic solvents?

S Barik, M Chakraborty, M Sarkar - The Journal of Physical …, 2020 - ACS Publications
In recent times, deep eutectic solvents (DESs) have emerged as an environment-friendly
alternative to both common organic solvents and ionic liquids (ILs). The present study has …