Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

[HTML][HTML] Surface organometallic and coordination chemistry toward single-site heterogeneous catalysts: strategies, methods, structures, and activities

C Coperet, A Comas-Vives, MP Conley… - Chemical …, 2016 - ACS Publications
The chemical industry relies on catalytic processes, which involve mainly heterogeneous
catalysts because they offer many advantages over their homogeneous counterparts such …

Surface organometallic chemistry in heterogeneous catalysis

MK Samantaray, E Pump… - Chemical Society …, 2018 - pubs.rsc.org
The broad challenges of energy and environment have become a main focus of research
efforts to develop more active and selective catalytic systems for key chemical …

[PDF][PDF] Triboelectrification-enabled self-powered detection and removal of heavy metal ions in wastewater

Z Li, J Chen, H Guo, X Fan, Z Wen, MH Yeh, C Yu… - Adv. Mater, 2016 - Citeseer
DOI: 10.1002/adma. 201504356 route that works in a self-powered manner by harnessing
the ambient energy using the triboelectrification effect. Relying on modified anodic …

The use of calixarenes in metal-based catalysis

DM Homden, C Redshaw - Chemical reviews, 2008 - ACS Publications
The condensation of formaldehyde with p-alkylphenols under alkaline conditions, a reaction
dating back to the days of Baeyer and Zinke, affords initially linear polyphenols, which, once …

β-cyclodextrin enhanced triboelectrification for self-powered phenol detection and electrochemical degradation

Z Li, J Chen, J Yang, Y Su, X Fan, Y Wu, C Yu… - Energy & …, 2015 - pubs.rsc.org
We report a unique route that creatively harnessed β-cyclodextrin enhanced
triboelectrification for self-powered phenol detection as well as electrochemical degradation …

Periodic Trends in Highly Dispersed Groups IV and V Supported Metal Oxide Catalysts for Alkene Epoxidation with H2O2

NE Thornburg, AB Thompson, JM Notestein - Acs Catalysis, 2015 - ACS Publications
Supported metal oxides are important catalysts for selective oxidation processes like alkene
epoxidation with H2O2. The reactivity of these catalysts is dependent on both identity and …

Enhancing heterogeneous catalysis through cooperative hybrid organic–inorganic interfaces

JM Notestein, A Katz - Chemistry–A European Journal, 2006 - Wiley Online Library
Active‐site/surface cooperativity can enhance heterogeneous organic and organometallic
catalysis. We review the powerful role of the solid surface in this context for generating local …

Alkene Epoxidations with H2O2 over Groups 4–6 Metal-Substituted BEA Zeolites: Reactive Intermediates, Reaction Pathways, and Linear Free-Energy …

EZ Ayla, DS Potts, DT Bregante, DW Flaherty - ACS Catalysis, 2020 - ACS Publications
Rates and selectivities for alkene epoxidations depend sensitively on the identity of the
active metal center for both heterogeneous and homogeneous catalysts. While group 6 …

New challenges in heterogeneous catalysis for the 21st century

F Zaera - Catalysis letters, 2012 - Springer
Heterogeneous catalysis has been around for a long time, but has still much room to grow.
The empirical trial-and-error mode used to develop catalysts in early times has progressively …