Recent Advances in First‐Row Transition‐Metal‐Mediated C− H Halogenation of (Hetero) arenes and Alkanes
The ubiquity of carbon halogen bonds in the structural core of numerous biomolecules and
pharmaceuticals along with their role as synthetic precursors in various organic reactions …
pharmaceuticals along with their role as synthetic precursors in various organic reactions …
Inspiration from Nature: influence of engineered ligand scaffolds and auxiliary factors on the reactivity of biomimetic oxidants
Enzymes are highly efficient catalysts in Nature that often react with high stereo-, chemo-,
and regioselectivity. Usually, enzymes achieve this selectivity through substrate binding and …
and regioselectivity. Usually, enzymes achieve this selectivity through substrate binding and …
Experimental and theoretical investigation of the tuning of electronic structure in SnO 2 via Co do** for enhanced styrene epoxidation catalysis
Exploiting new heterogeneous catalysts composed of earth-abundant elements for various
organic transformations under moderate reaction conditions is of vital importance in modern …
organic transformations under moderate reaction conditions is of vital importance in modern …
Carbamoyl manganese complexes for epoxidation of alkenes and cycloaddition of epoxides to carbon dioxide
H Hu, Y Li, Y Li, Y Ding, Y Sun, Y Li - Journal of Catalysis, 2023 - Elsevier
There is no precedent for the usage of transition metal carbamoyl complexes (typical
hydrogenase models) as pre-catalysts for oxidation or CO 2 utilization purposes. In this …
hydrogenase models) as pre-catalysts for oxidation or CO 2 utilization purposes. In this …
Advances in the synthesis and applications of macrocyclic polyamines
Y Gao, L Guo, X Liu, N Chen… - Royal Society Open …, 2024 - royalsocietypublishing.org
Macrocyclic polyamines constitute a significant class of macrocyclic compounds that play a
pivotal role in the realm of supramolecular chemistry. They find extensive applications …
pivotal role in the realm of supramolecular chemistry. They find extensive applications …
Theoretical exploration on structures, bonding aspects and molecular docking of α-aminophosphonate ligated copper complexes against SARS-CoV-2 proteases
Recent years have witnessed a growing interest in the biological activity of metal complexes
of α-aminophosphonates. Here for the first time, a detailed DFT study on five α …
of α-aminophosphonates. Here for the first time, a detailed DFT study on five α …
Comparative oxidative ability of mononuclear and dinuclear high-valent iron–oxo species towards the activation of methane: does the axial/bridge atom modulate the …
Over the years, mononuclear FeIVO species have been extensively studied, but the
presence of dinuclear FeIVO species in soluble methane monooxygenase (sMMO) has …
presence of dinuclear FeIVO species in soluble methane monooxygenase (sMMO) has …
Effect of Redox-Active Quinoline on the Reactivity and Mechanism of Hydrogen Evolution Reaction (HER) with Pentadentate Polypyridyl-Quinolyl Ligand-Coordinated …
Herein, we have introduced a redox-active quinoline moiety in a pentadentate pyridine-
containing N4Py ligand resulting in two quinolines and two pyridines containing 2PyN2Q …
containing N4Py ligand resulting in two quinolines and two pyridines containing 2PyN2Q …
A tale of two topological isomers: Uptuning [FeIV(O)(Me4cyclam)]2+ for olefin epoxidation
TMC-anti and TMC-syn, the two topological isomers of [FeIV (O)(TMC)(CH3CN)] 2+(TMC= 1,
4, 8, 11-tetramethyl-1, 4, 8, 11-tetraazacyclotetradecane, or Me4cyclam), differ in the …
4, 8, 11-tetramethyl-1, 4, 8, 11-tetraazacyclotetradecane, or Me4cyclam), differ in the …
Speciation Differences in the Surface Oxidizing Species on FeS2 and NiS2: Reactivity in Hydrogen Atom Transfer and Oxygen Atom Transfer
XB Zhang, H Tian, SH Wu, Y Liu… - ACS Earth and Space …, 2023 - ACS Publications
As the most abundant metal sulfide on Earth's surface, pyrite (FeS2) plays important roles in
the transformation of various elements and contaminants. Noteworthily, pyrite-type metal …
the transformation of various elements and contaminants. Noteworthily, pyrite-type metal …