Metallaaromatic chemistry: history and development

D Chen, Y Hua, H ** paradigms of chemical bonding: adaptive natural density partitioning
DY Zubarev, AI Boldyrev - Physical chemistry chemical physics, 2008 - pubs.rsc.org
A method of description of the chemical bonding combining the compactness and intuitive
simplicity of Lewis theory with the flexibility and generality of canonical molecular orbital …

Tailoring titanium carbide clusters for new materials: From met-cars to carbon-doped superatoms

C Cui, H Zhang, Y Gu, L Geng, Y Jia, S Lin… - Journal of the …, 2024 - ACS Publications
Tailoring materials with prescribed properties and regular structures is a critical and
challenging research topic. Early transition metals were found to form supermagic M8C12 …

Toward a consistent interpretation of the QTAIM: tortuous link between chemical bonds, interactions, and bond/line paths

C Foroutan‐Nejad, S Shahbazian… - Chemistry–A European …, 2014 - Wiley Online Library
Currently, bonding analysis of molecules based on the Quantum Theory of Atoms in
Molecules (QTAIM) is popular; however,“misinterpretations” of the QTAIM analysis are also …

Substantial π-aromaticity in the anionic heavy-metal cluster [Th@Bi12]4−

AR Eulenstein, YJ Franzke, N Lichtenberger… - Nature Chemistry, 2021 - nature.com
The concept of aromaticity was originally defined as a property of unsaturated, cyclic planar
organic molecules like benzene, which gain stability by the inherent delocalization of 4 n+ 2 …

A Neutral Planar Four-Membered Si2B2 2π-Aromatic Ring

SK Kushvaha, P Kallenbach, SS Rohman… - Journal of the …, 2023 - ACS Publications
The synthesis of the first inorganic four-membered neutral 2π-aromatic compound 2 is
reported. This unique ring has been synthesized from a simple and straightforward reaction …

Core-electron contributions to the magnetic response of molecules with heavy elements and their significance in aromaticity assessments

M Orozco-Ic, L Soriano-Agueda, D Sundholm… - Chemical …, 2024 - pubs.rsc.org
This study delves into the magnetic response of core electrons and their influence on the
global magnetic response of planar and three-dimensional systems containing heavy …

Recent development in the chemistry of transition metal-containing metallabenzenes and metallabenzynes

J Chen, G Jia - Coordination Chemistry Reviews, 2013 - Elsevier
Transition metal-containing metallabenzenes and metallabenzynes are organometallic
compounds derived from formal replacement of a CH group or a C atom in benzene and …