Sulfite-based advanced oxidation and reduction processes for water treatment

S Wu, L Shen, Y Lin, K Yin, C Yang - Chemical Engineering Journal, 2021 - Elsevier
Sulfite has attracted increasing attention as a precursor to produce highly reactive species to
eliminate pollutants from water due to the merits of abundant sources, low cost and low eco …

Reactive high-valent iron intermediates in enhancing treatment of water by ferrate

VK Sharma, M Feng, DD Dionysiou… - Environmental …, 2021 - ACS Publications
Efforts are being made to tune the reactivity of the tetraoxy anion of iron in the+ 6 oxidation
state (FeVIO42–), commonly called ferrate, to further enhance its applications in various …

Unraveling the overlooked involvement of high-valent cobalt-oxo species generated from the cobalt (II)-activated peroxymonosulfate process

Y Zong, X Guan, J Xu, Y Feng, Y Mao… - Environmental …, 2020 - ACS Publications
Sulfate radical (SO4•–) is widely recognized as the predominant species generated from the
cobalt (II)-activated peroxymonosulfate (PMS) process. However, in this study, it was …

Single-atom Fe catalyst outperforms its homogeneous counterpart for activating peroxymonosulfate to achieve effective degradation of organic contaminants

K Qian, H Chen, W Li, Z Ao, Y Wu… - Environmental Science & …, 2021 - ACS Publications
Recently, reactive iron species (RFeS) have shown great potential for the selective
degradation of emerging organic contaminants (EOCs). However, the rapid generation of …

Mn2O3 as an Electron Shuttle between Peroxymonosulfate and Organic Pollutants: The Dominant Role of Surface Reactive Mn(IV) Species

H Li, N Yuan, J Qian, B Pan - Environmental Science & …, 2022 - ACS Publications
The environmentally benign Mn oxides play a crucial role in the transformation of organic
contaminants, either through catalytically decomposing oxidants, eg, peroxymonosulfate …

Persulfate oxidation of sulfamethoxazole by magnetic iron-char composites via nonradical pathways: Fe (IV) versus surface-mediated electron transfer

J Liang, X Duan, X Xu, K Chen, Y Zhang… - Environmental …, 2021 - ACS Publications
Despite the vital roles of reactive radical species in the coupled iron–carbon
composite/persulfate (PS) system for eliminating pollutants, nonradical contributions are …

Enhanced oxidation of organic contaminants by iron (II)-activated periodate: the significance of high-valent iron–oxo species

Y Zong, Y Shao, Y Zeng, B Shao, L Xu… - Environmental …, 2021 - ACS Publications
Potassium periodate (PI, KIO4) was readily activated by Fe (II) under acidic conditions,
resulting in the enhanced abatement of organic contaminants in 2 min, with the decay ratios …

Improved electronic structure from spin-state reconstruction of a heteronuclear Fe–Co diatomic pair to boost the Fenton-like reaction

Z Zhao, M Hu, T Nie, W Zhou, B Pan… - … Science & Technology, 2023 - ACS Publications
Dual-atom catalysts (DACs) are promising candidates for various catalytic reactions,
including electrocatalysis, chemical synthesis, and environmental remediation. However, the …

Advanced oxidation process with peracetic acid and Fe (II) for contaminant degradation

J Kim, T Zhang, W Liu, P Du, JT Dobson… - … Science & Technology, 2019 - ACS Publications
Fe (II) is an excellent promoter for advanced oxidation processes (AOPs) because of its
environmental ubiquity and low toxicity. This study is among the first to characterize the …

Coupled surface-confinement effect and pore engineering in a single-Fe-atom catalyst for ultrafast Fenton-like reaction with high-valent iron-oxo complex oxidation

B Huang, Z Wu, X Wang, X Song, H Zhou… - Environmental …, 2023 - ACS Publications
The nanoconfinement effect in Fenton-like reactions shows great potential in environmental
remediation, but the construction of confinement structure and the corresponding …