The modular four-component carbonylation of unsaturated hydrocarbons represents an
elegant strategy for the one-pot synthesis of complex carbonyl compounds. However, this …

A redox-neutral copper-catalyzed cascade reaction involving alkoxyl radical-mediated ring
expansion/1, 4-difunctionalization of 1, 3-enynes was developed, offering a straightforward …

The construction of a small molecule library that includes compounds with medium-sized
rings is increasingly essential in drug discovery. These compounds are essential for …

An array of redox-neutral alkylation/cyclization cascade reactions of N-functionalized
acrylamides with cycloalkyl hydroperoxides were achieved via the alkoxyl radical-triggered …

This work discloses a two-step, one-pot approach to ω-functionalized esters via cleavage of
the alicyclic fragment of cycloalkanone semicarbazones. This approach is based on a …

This Feature Article discusses recent advances in the development of cascade ring
expansion reactions for the synthesis of medium-sized rings and macrocycles. Cascade ring …

The selective reaction of cyclic aminoperoxides with FeCl2 proceeds through a sequence of
O–O and C–C bond cleavages, followed by intramolecular cyclization, yielding …

An inexpensive iron-catalyzed alkoxyl radical-induced C–C bond cleavage/gem-
difluoroalkylation cascade is presented. Regulated by the structure of alkoxyl radical …

The development of general and practical strategies toward the construction of medium-
sized rings is still challenging in organic synthesis, especially for the multiple stereocenters …

A photoinduced copper-catalyzed alkoxyl triggered C− C bond cleavage/
aminocarbonylation cascade is presented. Through adjusting the structure of alkoxyl radical …