Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis

S Clair, DG de Oteyza - Chemical reviews, 2019 - ACS Publications
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …

Recent progress in on-surface synthesis of nanoporous graphene materials

T Qin, T Wang, J Zhu - Communications Chemistry, 2024 - nature.com
Nanoporous graphene (NPG) materials are generated by removing internal degree-3
vertices from graphene and introducing nanopores with specific topological structures …

Deceptive orbital confinement at edges and pores of carbon-based 1D and 2D nanoarchitectures

I Piquero-Zulaica, E Corral-Rascón… - Nature …, 2024 - nature.com
The electronic structure defines the properties of graphene-based nanomaterials. Scanning
tunneling microscopy/spectroscopy (STM/STS) experiments on graphene nanoribbons …

Constructing covalent organic nanoarchitectures molecule by molecule via scanning probe manipulation

Q Zhong, A Ihle, S Ahles, HA Wegner, A Schirmeisen… - Nature Chemistry, 2021 - nature.com
Constructing low-dimensional covalent assemblies with tailored size and connectivity is
challenging yet often key for applications in molecular electronics where optical and …

Synthesis of a porous [14] annulene graphene nanoribbon and a porous [30] annulene graphene nanosheet on metal surfaces

T Qin, D Guo, J **ong, X Li, L Hu, W Yang… - Angewandte …, 2023 - Wiley Online Library
The electrical and mechanical properties of graphene‐based materials can be tuned by the
introduction of nanopores, which are sensitively related to the size, morphology, density, and …

On-surface polyarylene synthesis by cycloaromatization of isopropyl substituents

A Kinikar, M Di Giovannantonio, JI Urgel, K Eimre… - Nature …, 2022 - nature.com
Immobilization of organic molecules on metal surfaces and their coupling via thermally
induced C–C bond formation is an important technique in organic and polymer synthesis …

The role of kinetics versus thermodynamics in surface-assisted Ullmann coupling on gold and silver surfaces

M Fritton, DA Duncan, PS Deimel… - Journal of the …, 2019 - ACS Publications
Surface-assisted Ullmann coupling is the workhorse of on-surface synthesis. Despite its
obvious relevance, many fundamental and mechanistic aspects remain elusive. To shed …

Planar π-extended cycloparaphenylenes featuring an all-armchair edge topology

F **ang, S Maisel, S Beniwal, V Akhmetov… - Nature Chemistry, 2022 - nature.com
Abstract The [n] cycloparaphenylenes ([n] CPPs)—n para-linked phenylenes that form a
closed-loop—have attracted substantial attention due to their unique cyclic structure and …

Confined on-surface organic synthesis: strategies and mechanisms

T Wang, J Zhu - Surface Science Reports, 2019 - Elsevier
On-surface synthesis has been one of the hottest research fields in surface science in the
last decade, owing to its great potential for bottom-up synthesis of functional molecules and …

Influence of molecular configurations on the desulfonylation reactions on metal surfaces

J Wang, K Niu, C Xu, H Zhu, H Ding… - Journal of the …, 2022 - ACS Publications
On-surface synthesis is a powerful methodology for the fabrication of low-dimensional
functional materials. The precursor molecules usually anchor on different metal surfaces via …