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Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …
creating new organic materials. A large number of chemical reactions have been …
Recent progress in on-surface synthesis of nanoporous graphene materials
Nanoporous graphene (NPG) materials are generated by removing internal degree-3
vertices from graphene and introducing nanopores with specific topological structures …
vertices from graphene and introducing nanopores with specific topological structures …
Deceptive orbital confinement at edges and pores of carbon-based 1D and 2D nanoarchitectures
I Piquero-Zulaica, E Corral-Rascón… - Nature …, 2024 - nature.com
The electronic structure defines the properties of graphene-based nanomaterials. Scanning
tunneling microscopy/spectroscopy (STM/STS) experiments on graphene nanoribbons …
tunneling microscopy/spectroscopy (STM/STS) experiments on graphene nanoribbons …
Constructing covalent organic nanoarchitectures molecule by molecule via scanning probe manipulation
Constructing low-dimensional covalent assemblies with tailored size and connectivity is
challenging yet often key for applications in molecular electronics where optical and …
challenging yet often key for applications in molecular electronics where optical and …
Synthesis of a porous [14] annulene graphene nanoribbon and a porous [30] annulene graphene nanosheet on metal surfaces
The electrical and mechanical properties of graphene‐based materials can be tuned by the
introduction of nanopores, which are sensitively related to the size, morphology, density, and …
introduction of nanopores, which are sensitively related to the size, morphology, density, and …
On-surface polyarylene synthesis by cycloaromatization of isopropyl substituents
Immobilization of organic molecules on metal surfaces and their coupling via thermally
induced C–C bond formation is an important technique in organic and polymer synthesis …
induced C–C bond formation is an important technique in organic and polymer synthesis …
The role of kinetics versus thermodynamics in surface-assisted Ullmann coupling on gold and silver surfaces
M Fritton, DA Duncan, PS Deimel… - Journal of the …, 2019 - ACS Publications
Surface-assisted Ullmann coupling is the workhorse of on-surface synthesis. Despite its
obvious relevance, many fundamental and mechanistic aspects remain elusive. To shed …
obvious relevance, many fundamental and mechanistic aspects remain elusive. To shed …
Planar π-extended cycloparaphenylenes featuring an all-armchair edge topology
Abstract The [n] cycloparaphenylenes ([n] CPPs)—n para-linked phenylenes that form a
closed-loop—have attracted substantial attention due to their unique cyclic structure and …
closed-loop—have attracted substantial attention due to their unique cyclic structure and …
Confined on-surface organic synthesis: strategies and mechanisms
On-surface synthesis has been one of the hottest research fields in surface science in the
last decade, owing to its great potential for bottom-up synthesis of functional molecules and …
last decade, owing to its great potential for bottom-up synthesis of functional molecules and …
Influence of molecular configurations on the desulfonylation reactions on metal surfaces
J Wang, K Niu, C Xu, H Zhu, H Ding… - Journal of the …, 2022 - ACS Publications
On-surface synthesis is a powerful methodology for the fabrication of low-dimensional
functional materials. The precursor molecules usually anchor on different metal surfaces via …
functional materials. The precursor molecules usually anchor on different metal surfaces via …