Functional metallofullerene materials and their applications in nanomedicine, magnetics, and electronics

T Wang, C Wang - Small, 2019 - Wiley Online Library
Endohedral metallofullerenes exhibit combined properties from carbon cages as well as
internal metal moieties and have great potential in a wide range of applications as molecule …

Molecular structures and magnetic properties of endohedral metallofullerenes

W Li, C Wang, T Wang - Chemical Communications, 2021 - pubs.rsc.org
Endohedral metallofullerenes have fascinating core–shell structures, with metal atoms or
metal clusters encaged in fullerene cages, and they display various chemical, optical and …

CaY@C2n: Exploring Molecular Qubits with Ca–Y Metal–Metal Bonds

J Qiu, L Abella, X Du, Z Cao, Z He… - Journal of the …, 2024 - ACS Publications
Metal–metal bonding is crucial in chemistry for advancing our understanding of the
fundamental aspects of chemical bonds. Metal–metal bonds based on alkaline-earth (Ae) …

Endohedral Metallofullerene as Molecular High Spin Qubit: Diverse Rabi Cycles in Gd2@C79N

Z Hu, BW Dong, Z Liu, JJ Liu, J Su, C Yu… - Journal of the …, 2018 - ACS Publications
An anisotropic high-spin qubit with long coherence time could scale the quantum system up.
It has been proposed that Grover's algorithm can be implemented in such systems …

Exploring the organometallic route to molecular spin qubits: The [CpTi (cot)] case

LC de Camargo, M Briganti, FS Santana… - Angewandte …, 2021 - Wiley Online Library
The coherence time of the 17‐electron, mixed sandwich complex [CpTi (cot)],(η8‐
cyclooctatetraene)(η5‐cyclopentadienyl) titanium, reaches 34 μs at 4.5 K in a frozen …

Structurally Defined Water‐Soluble Metallofullerene Derivatives towards Biomedical Applications

Y Li, R Biswas, WP Kopcha, T Dubroca… - Angewandte …, 2023 - Wiley Online Library
Endohedral metallofullerenes (EMFs) are excellent carriers of rare‐earth element (REE)
ions in biomedical applications because they preclude the release of toxic metal ions …

Dy 2@ C 79 N: a new member of dimetalloazafullerenes with strong single molecular magnetism

Y Wang, J **ong, J Su, Z Hu, F Ma, R Sun, X Tan… - Nanoscale, 2020 - pubs.rsc.org
Enhancing the exchange interaction between magnetic ions is a long-term target in
molecular magnetism. Endohedral metallofullerenes (EMFs) provide a possibility for …

Realizing solution-phase room temperature quantum coherence in a tetrathiafulvalene-based diradicaloid complex

LE McNamara, A Zhou, T Rajh, L Sun… - Cell Reports Physical …, 2023 - cell.com
Molecular electron spins are promising candidates as scalable and tunable qubits but often
suffer from undesirable decomposition pathways. Furthermore, significant spin-lattice …

Molecular Spin Qubits Impregnated in a Hexagonal Self-Ordered Mesoporous Silica

XF Jiang, ZB Hu, C Shao, Z Ouyang, Z Wang… - Chemistry of …, 2022 - ACS Publications
Quantum computing is one of the most important technologies in this century. As a class of
qubit material in quantum computing devices, molecule-based electron spin clusters have …

Coherent manipulation and quantum phase interference in a fullerene-based electron triplet molecular qutrit

YX Wang, Z Liu, YH Fang, S Zhou, SD Jiang… - NPJ Quantum …, 2021 - nature.com
High-spin magnetic molecules are promising candidates for quantum information
processing because their intrinsic multiplicity facilitates information storage and …