Click chemistry strategies for the accelerated synthesis of functional macromolecules

Z Geng, JJ Shin, Y **, CJ Hawker - Journal of Polymer Science, 2021 - Wiley Online Library
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …

Activated ester containing polymers: opportunities and challenges for the design of functional macromolecules

A Das, P Theato - Chemical Reviews, 2016 - ACS Publications
Rapidly growing demand of functional polymers in various interdisciplinary areas of
research has accentuated the need for modern synthetic tools to develop advanced …

A highly efficient single-chain metal–organic nanoparticle catalyst for alkyne–azide “click” reactions in water and in cells

Y Bai, X Feng, H **ng, Y Xu, BK Kim… - Journal of the …, 2016 - ACS Publications
We show that copper-containing metal–organic nanoparticles (MONPs) are readily
synthesized via Cu (II)-mediated intramolecular cross-linking of aspartate-containing …

Catalytic living ring-opening metathesis polymerization with Grubbs' second-and third-generation catalysts

M Yasir, P Liu, IK Tennie, AFM Kilbinger - Nature chemistry, 2019 - nature.com
In a conventional living ring-opening metathesis polymerization (ROMP), an equal number
of ruthenium complexes to the number of polymer chains synthesized are required. This can …

Orthogonal multiple click reactions in synthetic polymer chemistry

U Tunca - Journal of Polymer Science Part A: Polymer …, 2014 - Wiley Online Library
This review highlights the concept of multiple click reaction strategy which is utilized for
design and synthesis of well‐defined complex macromolecular structures as well as …

Selective and orthogonal post-polymerization modification using sulfur (vi) fluoride exchange (SuFEx) and copper-catalyzed azide–alkyne cycloaddition (CuAAC) …

JS Oakdale, L Kwisnek, VV Fokin - Macromolecules, 2016 - ACS Publications
Functional polystyrenes and polyacrylamides, containing combinations of fluorosulfate,
aromatic silyl ether, and azide side chains, were used as scaffolds to demonstrate the …

Multifaceted synthetic route to functional polyacrylates by transesterification of poly (pentafluorophenyl acrylates)

A Das, P Theato - Macromolecules, 2015 - ACS Publications
Synthesis of functional polyacrylates by 4-dimethylaminopyridine (DMAP) catalyzed trans-
esterification of poly (pentafluorophenyl acrylate)(polyPFPA) is reported. High fidelity and …

C− H Functionalization and Allylic Amination for Post‐Polymerization Modification of Polynorbornenes

SR Gitter, WP Teh, X Yang, AF Dohoda… - Angewandte Chemie …, 2023 - Wiley Online Library
Post‐polymerization modification (PPM) via direct C− H functionalization is a powerful
synthetic strategy to convert polymer feed‐stocks into value‐added products. We found that …

The role of mass and length in the sonochemistry of polymers

M Schaefer, B Icli, C Weder, M Lattuada… - …, 2016 - ACS Publications
The ultrasound-induced cleavage of macromolecules has become a routine experiment in
the emerging field of polymer mechanochemistry. To date, it has not been conclusively …

A library of multifunctional polyesters with “peptide-like” pendant functional groups

S Gokhale, Y Xu, A Joy - Biomacromolecules, 2013 - ACS Publications
The synthesis and characterization of a library of modular multifunctional polyesters with
pendant functional groups are described. The polyesters were synthesized at room …