MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
Metal–organic framework-based catalysts with single metal sites
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
Mixed-metal metal–organic frameworks
Mixed-metal MOFs are metal–organic frameworks that contain at least 2 different metal ions
as nodes of their frameworks. They are prepared relatively easily by either a one-pot …
as nodes of their frameworks. They are prepared relatively easily by either a one-pot …
Pore surface engineering of metal–organic frameworks for heterogeneous catalysis
Y Wen, J Zhang, Q Xu, XT Wu, QL Zhu - Coordination Chemistry Reviews, 2018 - Elsevier
Abstract Metal–organic frameworks (MOFs), a class of emerging crystalline porous
materials, have received great attention for their prospective applications in various areas. In …
materials, have received great attention for their prospective applications in various areas. In …
Facile and green synthesis of metal-organic framework/inorganic nanofiber using electrospinning for recyclable visible-light photocatalysis
Herein, Fe based metal-organic framework (Materials Institute Lavoisier: MIL100) and its
nanocomposites with different titania nanofiber (TNF) amounts (0.05, 0.07 and 0.09 g …
nanocomposites with different titania nanofiber (TNF) amounts (0.05, 0.07 and 0.09 g …
Metal-organic-framework-based materials as green catalysts for alcohol oxidation
G An, X Zhang, C Zhang, H Gao, S Liu, G Qin… - Chinese Journal of …, 2023 - Elsevier
The selective oxidation of alcohols is widely regarded as one of the most important reactions
in organic synthesis. Although efficient and environmentally friendly catalysts for alcohol …
in organic synthesis. Although efficient and environmentally friendly catalysts for alcohol …
Electrochemical polarization of disparate catalytic sites drives thermochemical rate enhancement
Supported bimetallic catalysts commonly exhibit higher rates of reaction compared to their
monometallic counterparts, but the origin of these enhancements is often poorly defined …
monometallic counterparts, but the origin of these enhancements is often poorly defined …
Metal-free activation of molecular oxygen by covalent triazine frameworks for selective aerobic oxidation
Oxygen activation is a critical step in ubiquitous heterogeneous oxidative processes, most
prominently in catalysis, electrolysis, and pharmaceutical applications. We present here our …
prominently in catalysis, electrolysis, and pharmaceutical applications. We present here our …
Probing the evolution of palladium species in Pd@ MOF catalysts during the heck coupling reaction: an operando X-ray absorption spectroscopy study
The mechanism of the Heck C–C coupling reaction catalyzed by Pd@ MOFs has been
investigated using operando X-ray absorption spectroscopy (XAS) and powder X-ray …
investigated using operando X-ray absorption spectroscopy (XAS) and powder X-ray …
Tuneable nature of metal organic frameworks as heterogeneous solid catalysts for alcohol oxidation
Selective benzyl alcohol oxidation (BA) to benzaldehyde has been frequently used as a
benchmark reaction to evaluate the catalytic activity of metal organic frameworks (MOFs) as …
benchmark reaction to evaluate the catalytic activity of metal organic frameworks (MOFs) as …