Current progress in 2D metal–organic frameworks for electrocatalysis

U Khan, A Nairan, J Gao, Q Zhang - Small Structures, 2023 - Wiley Online Library
The 2D nanosheets of metal–organic frameworks (MOFs) have recently emerged as a
promising material that makes them valuable in widespread electrocatalytic fields due to …

Unlocking efficiency: minimizing energy loss in electrocatalysts for water splitting

W Li, Y Liu, A Azam, Y Liu, J Yang, D Wang… - Advanced …, 2024 - Wiley Online Library
Catalysts play a crucial role in water electrolysis by reducing the energy barriers for
hydrogen and oxygen evolution reactions (HER and OER). Research aims to enhance the …

Boosting toluene deep oxidation by tuning metal-support interaction in MOF-derived Pd@ ZrO2 catalysts: the role of interfacial interaction between Pd and ZrO2

F Bi, S Ma, B Gao, B Liu, Y Huang, R Qiao, X Zhang - Fuel, 2024 - Elsevier
The regulation of metal-support interaction is one of the productive strategies to enhance
volatile organic compounds (VOCs) deep degradation. Herein, Pd@ ZrO 2 catalysts were …

Electronic state and microenvironment modulation of metal nanoparticles stabilized by MOFs for boosting electrocatalytic nitrogen reduction

L Wen, K Sun, X Liu, W Yang, L Li… - Advanced …, 2023 - Wiley Online Library
Modulation of the local electronic structure and microenvironment of catalytic metal sites
plays a critical role in electrocatalysis, yet remains a grand challenge. Herein, PdCu …

Surface-Clean Au25 Nanoclusters in Modulated Microenvironment Enabled by Metal–Organic Frameworks for Enhanced Catalysis

H Wang, X Liu, W Yang, G Mao, Z Meng… - Journal of the …, 2022 - ACS Publications
Metal nanoclusters (NCs) with atomically precise structures have sparked interest in
catalysis. Unfortunately, their high aggregation tendency and the spatial resistance of …

Confining Ti-oxo clusters in covalent organic framework micropores for photocatalytic reduction of the dominant uranium species in seawater

S Zhang, L Chen, Z Qu, F Zhai, X Yin, D Zhang, Y Shen… - Chem, 2023 - cell.com
Photocatalytic reduction is a promising strategy for uranium extraction from seawater.
However, due to the lack of accessible active sites, current photocatalysts work poorly under …

The promoting effect of H2O on rod-like MnCeOx derived from MOFs for toluene oxidation: A combined experimental and theoretical investigation

X Zhang, F Bi, Z Zhu, Y Yang, S Zhao, J Chen… - Applied Catalysis B …, 2021 - Elsevier
Herein, a series of rod-like MnCeO x are synthesized by pyrolyzing Mn/Ce-BTC for toluene
oxidation. The 3Mn2Ce catalyst exhibits superior catalytic performance and stability under …

Electronic modulation caused by interfacial Ni‐O‐M (M= Ru, Ir, Pd) bonding for accelerating hydrogen evolution kinetics

L Deng, F Hu, M Ma, SC Huang, Y **ong… - Angewandte Chemie …, 2021 - Wiley Online Library
Designing definite metal‐support interfacial bond is an effective strategy for optimizing the
intrinsic activity of noble metals, but rather challenging. Herein, a series of quantum‐sized …

Linker Engineering of Sandwich‐Structured Metal–Organic Framework Composites for Optimized Photocatalytic H2 Production

S Wang, Z Ai, X Niu, W Yang, R Kang, Z Lin… - Advanced …, 2023 - Wiley Online Library
While the microenvironment around catalytic sites is recognized to be crucial in
thermocatalysis, its roles in photocatalysis remain subtle. In this work, a series of sandwich …

Robust Fluorine-Functionalized {Ln5}-Organic Frameworks for Excellent Catalytic Performance on Cycloaddition of CO2 with Epoxides and Knoevenagel …

C Li, H Lv, K Yang, X Zhang - ACS Applied Materials & Interfaces, 2023 - ACS Publications
Lanthanide–organic frameworks (LnOFs) are a class of promising catalysts on a large
number of organic reactions because of the higher coordination number of Ln3+ ions …