The cooperation and interplay between organic and metal catalyst systems is of utmost
importance in nature and chemical synthesis. Here innovative and selective cooperative …

Functionalized 4H‐chromenes represent one class of the most important structural scaffolds
in both synthetic and medicinal chemistry. They often appear in an arrange of biological …

In recent years, enantioselective cooperative catalytic reactions, wherein two catalysts work
simultaneously to form products which cannot be obtained by the use of a single catalyst …

The first one‐pot enantioselective oxidative coupling of cyclic benzylic ethers with aldehydes
has been developed. A variety of benzylic ethers were transformed into the corresponding …

A direct enantioselective synthesis of substituted oxygen heterocycles from lactol acetates
and enolsilanes has been realized using a highly reactive and confined …

The transformation of ortho‐alkynylaryl ketones through a cyclization/enantioselective‐
reduction sequence in the presence of a chiral silver phosphate catalyst afforded 1H …

Two catalysts, an amine HCl salt and a bisthiourea, work in concert to enable the generation
of oxocarbenium ions under mild conditions. The amine catalyst generates an iminium ion of …

Two enantioselective total syntheses of the nortriterpenoid natural product rubriflordilactone
A are described, which use palladium‐or cobalt‐catalyzed cyclizations to form the CDE …

A highly enantioselective carboalkoxylation of alkynes catalyzed by cationic (DTBM-MeO-
Biphep) gold (I) complexes is reported. Various optically active β-alkoxyindanone …

A new method has been developed for the catalytic asymmetric synthesis of α-chiral linear
or carbocyclic (γ-alkoxyallyl) boronates via the copper (I)-catalyzed γ-boryl substitution of …