This review surveys recent progress in the chemistry of polycyclic heteroaromatic molecules
with a focus on structural diversity and synthetic methodology. The article covers literature …

The formation of chiral nanostructures via molecular assembly and reaction on solid
surfaces is a ubiquitous surface process due to the symmetry-breaking at 2D surface …

Investigation of chirality in on-surface synthesis is of significance not only for fabricating
atomically precise covalently bonded chiral species but also for unveiling chiral phenomena …

Polyacene analogues, consisting of short acene segments separated by nonbenzenoid
rings, offer intriguing electronic properties and magnetic interactions. Pentalene-bridged …

On‐surface chemistry holds the potential for ultimate miniaturization of functional devices.
Porphyrins are promising building‐blocks in exploring advanced nanoarchitecture concepts …

Controlling the synthesis of low-dimensional chiral nanostructures on solid surfaces has
attracted tremendous interest in recent years. Herein, we report a study showing substrate …

Using density functional theory, we study the adsorption of cysteine molecules on the
monolayer, AB bilayer, and bilayer graphene with β= 32.20°, 27.79°, and 5.08° as twist …

Methods to control chiral-selectivity in molecular reactions through external inputs are of
importance, both from a fundamental and technological point of view. Here, the self …

This study investigates the synthesis of tetra‐and octa‐O‐fused porphyrinoids employing an
oxidative O‐annulation approach through C− H activation. Despite encountering challenges …

Porphyrin-based oligomers were synthesized from the condensation of adsorbed 4-
benzaldehyde-substituted porphyrins through the formation of CC linkages, following a …