Catalytic Dibenzocyclooctene Synthesis via Cobalt(III)–Carbene Radical and ortho‐Quinodimethane Intermediates

C Te Grotenhuis, N van den Heuvel… - Angewandte Chemie …, 2018 - Wiley Online Library
The metalloradical activation of ortho‐benzallylaryl N‐tosyl hydrazones with [Co
(TPP)](TPP= tetraphenylporphyrin) as the catalyst enabled the controlled exploitation of the …

[Co (TPP)]‐catalyzed formation of substituted piperidines

M Lankelma, AM Olivares… - Chemistry–A European …, 2019 - Wiley Online Library
Radical cyclization via cobalt (III)‐carbene radical intermediates is a powerful method for the
synthesis of (hetero) cyclic structures. Building on the recently reported synthesis of five …

Radical-type reactions controlled by cobalt: from carbene radical reactivity to the catalytic intermediacy of reactive o-quinodimethanes

C te Grotenhuis, B de Bruin - Synlett, 2018 - thieme-connect.com
In this account, we summarize our recent efforts in the fields of 'open-shell organometallic
chemistry'and 'metalloradical catalysis'. We focus in particular on the use of so-called …

Metalloradical Reactivity of RuI and Ru0 Stabilized by an Indole‐Based Tripodal Tetraphosphine Ligand

FF van de Watering, JI van der Vlugt… - … A European Journal, 2017 - Wiley Online Library
Abstract The tripodal, tetradentate tris (1‐(diphenylphosphanyl)‐3‐methyl‐1H‐indol‐2‐yl)
phosphane PP3‐ligand 1 stabilizes Ru in the RuII, RuI, and Ru0 oxidation states. The …

[BOOK][B] Transition-Metal-Catalyzed Reactions: Harnessing Metals to Facilitate Organic Transformation

AM Parsons - 2019 - search.proquest.com
Transition-metal-catalyzed reactions have revolutionized the field of organic chemistry,
enabling for the efficient synthesis of biologically and pharmaceutically relevant molecules …

Chemistry in Real Life: The Effect of Context-Based Learning on Student Participation in Remote Workshops

C Getz, J Mathew, G Shin - 2021 - urresearch.rochester.edu
Due to the COVID-19 pandemic, undergraduate student education has shifted to a larger
online format, and it is unclear how student education has been impacted. However, it has …