Functionalization of fluorinated molecules by transition-metal-mediated C–F bond activation to access fluorinated building blocks

T Ahrens, J Kohlmann, M Ahrens, T Braun - Chemical Reviews, 2015 - ACS Publications
Fluorinated organic compounds increasingly gain importance in numerous areas of
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …

Lanthanide photocatalysis

Y Qiao, EJ Schelter - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus The use of earth-abundant, cheap, potent, and readily available lanthanide
photocatalysts provides an opportunity to complement or even replace rare and precious …

Molybdenum-catalysed ammonia production with samarium diiodide and alcohols or water

Y Ashida, K Arashiba, K Nakajima, Y Nishibayashi - Nature, 2019 - nature.com
The production of ammonia from nitrogen gas is one of the most important industrial
processes, owing to the use of ammonia as a raw material for nitrogen fertilizers. Currently …

Coordination-induced bond weakening

NG Boekell, RA Flowers - Chemical Reviews, 2022 - ACS Publications
Coordination-induced bond weakening is a phenomenon wherein ligand X–H bond
homolysis occurs in concert with the energetically favorable oxidation of a coordinating …

Metal-mediated reductive hydrodehalogenation of organic halides

F Alonso, IP Beletskaya, M Yus - Chemical reviews, 2002 - ACS Publications
Organic halides are very important and versatile compounds with many applications as
starting materials, solvents, reagents, and intermediates in synthetic organic chemistry. 1 …

Synthesis of fluorinated building blocks by transition‐metal‐mediated hydrodefluorination reactions

MF Kuehnel, D Lentz, T Braun - … Chemie International Edition, 2013 - Wiley Online Library
The activation and functionalization of carbon–fluorine bonds can be considered as a major
challenge in organometallic chemistry. The growing demand for means to introduce fluorine …

Activation of carbon-fluorine bonds by metal complexes

JL Kiplinger, TG Richmond, CE Osterberg - Chemical Reviews, 1994 - ACS Publications
An area of research that has recently attracted the attention of inorganic and organometallic
chemists is the coordination and activation of fluorocarbons by transition-metal complexes. 1 …

Photodriven Sm (III)-to-Sm (II) Reduction for Catalytic Applications

CM Johansen, EA Boyd, DE Tarnopol… - Journal of the American …, 2024 - ACS Publications
The selectivity of SmI2 as a one electron-reductant motivates the development of methods
for reductive Sm-catalysis. Photochemical methods for SmI2 regeneration are desired for …

Treatment technologies for aqueous perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA)

CD Vecitis, H Park, J Cheng, BT Mader… - … Science & Engineering …, 2009 - Springer
Fluorochemicals (FCs) are oxidatively recalcitrant, environmentally persistent, and resistant
to most conventional treatment technologies. FCs have unique physiochemical properties …

[BUKU][B] Metal dihydrogen and s-bond complexes: structure, theory, and reactivity

GJ Kubas - 2001 - books.google.com
According to RH Crabtree, Metal Dihydrogen and sigma-Bond Complexes is described
asthe definitive account of twentieth-century work in the area of sigma complexation'. It …