Proton transport in metal–organic frameworks

DW Lim, H Kitagawa - Chemical reviews, 2020 - ACS Publications
Solid-state proton conductors (SSPCs), which are a key component for the safety and
efficiency of fuel cells, have received much attention due to their broad application in …

Rational designs for highly proton-conductive metal− organic frameworks

M Sadakiyo, T Yamada, H Kitagawa - Journal of the American …, 2009 - ACS Publications
A novel metal− organic framework (MOF),(NH4) 2 (adp)[Zn2 (ox) 3]· 3H2O (1) was
synthesized and its structure was determined. We propose three types of rational design to …

Helical Water Chain Mediated Proton Conductivity in Homochiral Metal–Organic Frameworks with Unprecedented Zeolitic unh-Topology

SC Sahoo, T Kundu, R Banerjee - Journal of the American …, 2011 - ACS Publications
Four new homochiral metal–organic framework (MOF) isomers,[Zn (lL Cl)(Cl)](H2O) 2 (1),[Zn
(lL Br)(Br)](H2O) 2 (2),[Zn (dL Cl)(Cl)](H2O) 2 (3), and [Zn (dL Br)(Br)](H2O) 2 (4)[L= 3-methyl …

Promotion of low-humidity proton conduction by controlling hydrophilicity in layered metal–organic frameworks

M Sadakiyo, H O̅kawa, A Shigematsu… - Journal of the …, 2012 - ACS Publications
We controlled the hydrophilicity of metal–organic frameworks (MOFs) to achieve high proton
conductivity and high adsorption of water under low humidity conditions, by employing novel …

Control of crystalline proton-conducting pathways by water-induced transformations of hydrogen-bonding networks in a metal–organic framework

M Sadakiyo, T Yamada, K Honda… - Journal of the …, 2014 - ACS Publications
Structure-defined metal–organic frameworks (MOFs) are of interest because rational design
and construction allow us to develop good proton conductors or possibly control the proton …

A europium (III) based metal–organic framework: Bifunctional properties related to sensing and electronic conductivity

Z Hao, G Yang, X Song, M Zhu, X Meng… - Journal of Materials …, 2014 - pubs.rsc.org
The accessible interspace of [Eu4 (BPT) 4 (DMF) 2 (H2O) 8](EuL) metal–organic framework
(MOF) based host materials can serve as good candidates for loading of a variety of guest …

Step-by-step fabrication of a highly oriented crystalline three-dimensional pillared-layer-type metal–organic framework thin film confirmed by synchrotron X-ray …

K Otsubo, T Haraguchi, O Sakata… - Journal of the …, 2012 - ACS Publications
Fabrication of a crystalline ordered thin film based on the porous metal–organic frameworks
(MOFs) is one of the practical applications of the future functional nanomaterials. Here, we …

Electrically conductive 1D coordination polymers: design strategies and controlling factors

F Ahmed, B Dutta, MH Mir - Dalton Transactions, 2021 - pubs.rsc.org
Due to the easy functionality and structural diversity of coordination polymers (CPs) coupled
with superior thermal stability, many researchers have been prompted to explore the …

Design and synthesis of hydroxide ion–conductive metal–organic frameworks based on salt inclusion

M Sadakiyo, H Kasai, K Kato, M Takata… - Journal of the …, 2014 - ACS Publications
We demonstrate a metal–organic framework (MOF) design for the inclusion of hydroxide
ions. Salt inclusion method was applied to an alkaline-stable ZIF-8 (ZIF= zeolitic imidazolate …

[PDF][PDF] Two Linear Undecanickel Mixed‐Valence Complexes: Increasing the Size and the Scope of the Electronic Properties of Nickel Metal Strings

RH Ismayilov, WZ Wang, GH Lee, CY Yeh… - Angewandte Chemie …, 2011 - academia.edu
The importance of one-dimensional (1D) transition-metal complexes stems from their ability
to provide a fundamental understanding of metal–metal interactions and electron transport …