Elucidating the formation and structural evolution of platinum single-site catalysts for the hydrogen evolution reaction

P Tang, HJ Lee, K Hurlbutt, PY Huang… - ACS …, 2022 - ACS Publications
Platinum single-site catalysts (SSCs) are a promising technology for the production of
hydrogen from clean energy sources. They have high activity and maximal platinum-atom …

Mechanoresponsive metal‐organic cage‐crosslinked polymer hydrogels

R Küng, A Germann, M Krüsmann… - … A European Journal, 2023 - Wiley Online Library
We report the formation of metal‐organic cage‐crosslinked polymer hydrogels. To enable
crosslinking of the cages and subsequent network formation, we used homodifunctionalized …

Stabilization of the Pd–NHC framework with 1, 2, 4-triazol-5-ylidene ligands toward decomposition in alkaline media

AY Chernenko, AV Astakhov, VV Kutyrev… - Inorganic Chemistry …, 2021 - pubs.rsc.org
Complexes of Pd (II) with NHC ligands can suffer facile decomposition in the presence of
alkali metal hydroxides, alkoxydes and other strong oxygen-containing bases via the …

Selective Buchwald–Hartwig arylation of C-amino-1, 2, 4-triazoles and other coordinating aminoheterocycles enabled by bulky NHC ligands and TPEDO activator

AV Astakhov, AY Chernenko, VV Kutyrev… - Inorganic Chemistry …, 2023 - pubs.rsc.org
C-Amino-1, 2, 4-triazoles are challenging polynitrogen substrates for metal-catalyzed
arylation due to their multidentate character, enhanced coordinating ability and decreased …

Dimroth rearrangement “thiadiazole-triazole”: synthesis and exploration of 3-sulfanyl-1, 2, 4-triazolium salts as NHC-proligands

DV Pasyukov, AY Chernenko, IV Lavrentev… - Russian Chemical …, 2022 - Springer
Abstract The reaction of 1, 4-disubstituted thiosemicarbazides with N, N-dimethylformamide
dimethyl acetal afforded 1, 4-disubstituted 1, 2, 4-triazolium-3-thiolates. Heating of the …

Base‐Ionizable Anionic NHC Ligands in Pd‐catalyzed Reactions of Aryl Chlorides

AY Chernenko, VA Baydikova, VV Kutyrev… - …, 2024 - Wiley Online Library
Aryl chlorides, due to their affordability and accessibility, are preferred reagents in Pd‐
catalyzed arylation reactions. However, the reactivity of aryl chlorides is often lower than that …

NHC Pdii complexes for the solvent-free telomerisation of isoprene with methanol

SA Rzhevskiy, MA Topchiy, VN Bogachev… - Mendeleev …, 2021 - Elsevier
A comparative study of N-heterocyclic carbene Pd complexes in the head-to-head isoprene
telomerization with methanol revealed significant impact of ligand structure as well as axial …

N, S-heterocyclic carbene containing benzothiazol-2-ylidene-Ru (II) and Pd (II) new complexes functionalized with butyl linked carbazole moiety: Synthesis …

H Karakaş, M Güzel, M Ak, R Kılınçarslan… - European Polymer …, 2022 - Elsevier
In contrast to the large number of polymeric N-heterocyclic carbenes (NHCs) there are
relatively few examples of NHCs-containing conductive polymers. However, conducting …

Polymetallic magnetic palladium catalysts for the Suzuki reaction in aqueous media

NA Bumagin - Russian Chemical Bulletin, 2021 - Springer
A mechanochemical method for the synthesis of Pd-Fe-Co-Ni ferromagnetic composites was
developed. The composites are highly efficient catalysts for the Suzuki reaction in aqueous …

A study of the reactivity and transformations of Pd/NHC complexes in the reaction of oxidative C− H acetoxylation

VV Chesnokov, MA Shevchenko… - Russian Chemical Bulletin, 2022 - Springer
A comparative study of the reactivity and transformation and degradation pathways under
conditions of the oxidative acetoxylation was carried out for various palladium complexes …