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P-Stereogenic phosphorus ligands in asymmetric catalysis
T Imamoto - Chemical reviews, 2024 - ACS Publications
Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …
synthesis of useful optically active compounds. They are largely categorized into two …
Recent advances in the enantioselective synthesis of chiral amines via transition metal-catalyzed asymmetric hydrogenation
Chiral amines are key structural motifs present in a wide variety of natural products, drugs,
and other biologically active compounds. During the past decade, significant advances have …
and other biologically active compounds. During the past decade, significant advances have …
Photochemical single-step synthesis of β-amino acid derivatives from alkenes and (hetero) arenes
Abstract β-Amino acids are frequently found as important components in numerous
biologically active molecules, drugs and natural products. In particular, they are broadly …
biologically active molecules, drugs and natural products. In particular, they are broadly …
Cooperative carbene photocatalysis for β-amino ester synthesis
β-Amino acids are useful building blocks of bioactive molecules, including peptidomimetics
and pharmaceutical compounds. The current limited accessibility to β2, 2-type amino acids …
and pharmaceutical compounds. The current limited accessibility to β2, 2-type amino acids …
Enzymatic asymmetric synthesis of chiral amino acids
Chiral amino acids are extensively applied in the pharmaceutical, food, cosmetic,
agricultural, and feedstuff industries. The development of synthetic methodologies for …
agricultural, and feedstuff industries. The development of synthetic methodologies for …
Discovery, engineering, and synthetic application of transaminase biocatalysts
Transaminases have attracted considerable interest in their use as biocatalysts for the
synthesis of compounds containing chiral amine units, which are widespread within the …
synthesis of compounds containing chiral amine units, which are widespread within the …
Mechanochemical and mechanoenzymatic synthesis of pharmacologically active compounds: A green perspective
Recently, the application of mechanochemical strategies in organic synthesis has attracted
the attention of both the academic and industrial chemical communities. The high efficiency …
the attention of both the academic and industrial chemical communities. The high efficiency …
Ligand-Enabled γ-C(sp3)–H Hydroxylation of Free Amines with Aqueous Hydrogen Peroxide
Selective oxidation of the γ-C–H bonds from abundant amine feedstocks via palladium
catalysis is a valuable transformation in synthesis and medicinal chemistry. Despite …
catalysis is a valuable transformation in synthesis and medicinal chemistry. Despite …
Rhodium-catalysed asymmetric hydrogenation as a valuable synthetic tool for the preparation of chiral drugs
During the last few decades, rhodium-catalysed asymmetric hydrogenation of diverse
alkene classes has emerged as a powerful synthetic tool in the pharmaceutical industry …
alkene classes has emerged as a powerful synthetic tool in the pharmaceutical industry …
Tailor‐made amino acids and fluorinated motifs as prominent traits in modern pharmaceuticals
Structural analysis of modern pharmaceutical practices allows for the identification of two
rapidly growing trends: the introduction of tailor‐made amino acids and the exploitation of …
rapidly growing trends: the introduction of tailor‐made amino acids and the exploitation of …