Recent years have witnessed the emergence of direct intermolecular C (sp3)–H bond
functionalization using in situ generated aryl/alkyl radicals as a unique class of hydrogen …

The advancement in electrochemical techniques has unlocked a new path for achieving
unprecedented oxidations and reductions of aryl radical precursors in a controlled and …

A practical denitrative cyanation of feedstock nitroarenes under mild and transition metal-
free reaction conditions has been developed. The key to success lies in the use of …

Aryl radicals are important intermediates in organic synthesis. The generation of these
reactive species via direct decarboxylation of inexpensive and readily available aromatic …

Herein, we report a visible light-induced diheteroarylation reaction of [1.1. 1] propellane to
synthesize 1, 3-diheteroaryl bicyclo [1.1. 1] pentanes (BCPs). In this approach, heteroaryl …

A new strategy for the metal-free photoinduced activation of p-methoxybenzyl esters is
developed using Selectfluor and benzil for the generation of acyl fluoride intermediates that …

Given the widespread presence of spirocyclic scaffolds in natural products and
pharmacologically relevant synthetic compounds, the development of efficient …

An electrochemical protocol for the alkylthiolation of aryl halides was developed. By using
dialkyl disulfides as the alkylthio sources, Mg plate as the sacrificial anode and graphite felt …

Efficient cyclization reactions play a pivotal role in the synthesis of extended polycyclic
aromatic hydrocarbons (PAHs) and graphene nanoribbons. Although efficient reactions …

Photoredox-catalyzed phosphonylation of bromo-substituted 1, 10-phenanthrolines under
visible light irradiation was studied. The reaction was shown to proceed under mild …