Mechanically interlocked polymers based on rotaxanes

L Chen, X Sheng, G Li, F Huang - Chemical Society Reviews, 2022 - pubs.rsc.org
The nature of mechanically interlocked molecules (MIMs) has continued to encourage
researchers to design and construct a variety of high-performance materials. Introducing …

Stimuli-responsive mechanically interlocked molecules constructed from cucurbit [n] uril homologues and derivatives

JX Liu, K Chen, C Redshaw - Chemical Society Reviews, 2023 - pubs.rsc.org
Cucurbit [n] uril supramolecular chemistry has developed rapidly since 2001 when different
cucurbit [n] uril homologues (Q [n]) were successfully separated in pure form. The …

Chemically fueled self‐assembly in biology and chemistry

K Das, L Gabrielli, LJ Prins - Angewandte Chemie International …, 2021 - Wiley Online Library
Life is a non‐equilibrium state of matter maintained at the expense of energy. Nature uses
predominantly chemical energy stored in thermodynamically activated, but kinetically stable …

An electric molecular motor

L Zhang, Y Qiu, WG Liu, H Chen, D Shen, B Song… - Nature, 2023 - nature.com
Macroscopic electric motors continue to have a large impact on almost every aspect of
modern society. Consequently, the effort towards develo** molecular motors,–that can be …

Material properties and applications of mechanically interlocked polymers

LF Hart, JE Hertzog, PM Rauscher, BW Rawe… - Nature Reviews …, 2021 - nature.com
Mechanically interlocked polymers (MIPs), such as polyrotaxanes and polycatenanes, are
polymer architectures that incorporate a mechanical bond. In a polyrotaxane, the …

A catalysis-driven artificial molecular pump

S Amano, SDP Fielden, DA Leigh - Nature, 2021 - nature.com
All biological pumps are autonomous catalysts; they maintain the out-of-equilibrium
conditions of the cell by harnessing the energy released from their catalytic decomposition of …

Active mechanisorption driven by pum** cassettes

L Feng, Y Qiu, QH Guo, Z Chen, JSW Seale, K He… - Science, 2021 - science.org
Over the past century, adsorption has been investigated extensively in equilibrium systems,
with a focus on the van der Waals interactions associated with physisorption and electronic …

Molecular pumps and motors

Y Feng, M Ovalle, JSW Seale, CK Lee… - Journal of the …, 2021 - ACS Publications
Pumps and motors are essential components of the world as we know it. From the complex
proteins that sustain our cells, to the mechanical marvels that power industries, much we …

Single‐Ion‐Conducting Hydrogel Electrolytes Based on Slide‐Ring Pseudo‐Polyrotaxane for Ultralong‐Cycling Flexible Zinc‐Ion Batteries

H **a, G Xu, X Cao, C Miao, H Zhang… - Advanced …, 2023 - Wiley Online Library
Flexible zinc‐ion batteries (ZIBs) with high capacity and long cycle stability are essential for
wearable electronic devices. Hydrogel electrolytes have been developed to provide ion …

Formation of polyrotaxane crystals driven by dative boron–nitrogen bonds

X **ao, D **ao, G Sheng, T Shan, J Wang, X Miao… - Science …, 2023 - science.org
The integration of mechanically interlocked molecules (MIMs) into purely organic crystalline
materials is expected to produce materials with properties that are not accessible using …