Oxygen loss in layered oxide cathodes for Li-ion batteries: mechanisms, effects, and mitigation

H Zhang, H Liu, LFJ Piper, MS Whittingham… - Chemical …, 2022 - ACS Publications
Layered lithium transition metal oxides derived from LiMO2 (M= Co, Ni, Mn, etc.) have been
widely adopted as the cathodes of Li-ion batteries for portable electronics, electric vehicles …

Challenges and recent advances in high capacity Li‐rich cathode materials for high energy density lithium‐ion batteries

W He, W Guo, H Wu, L Lin, Q Liu, X Han… - Advanced …, 2021 - Wiley Online Library
Li‐rich cathode materials have attracted increasing attention because of their high reversible
discharge capacity (> 250 mA hg− 1), which originates from transition metal (TM) ion redox …

Origin of structural degradation in Li-rich layered oxide cathode

T Liu, J Liu, L Li, L Yu, J Diao, T Zhou, S Li, A Dai… - Nature, 2022 - nature.com
Li-and Mn-rich (LMR) cathode materials that utilize both cation and anion redox can yield
substantial increases in battery energy density,–. However, although voltage decay issues …

A Li-rich layered oxide cathode with negligible voltage decay

D Luo, H Zhu, Y **a, Z Yin, Y Qin, T Li, Q Zhang, L Gu… - Nature Energy, 2023 - nature.com
With high capacity at low cost, Li-and Mn-rich (LMR) layered oxides are a promising class of
cathodes for next-generation Li-ion batteries. However, substantial voltage decay during …

VOC Bonding of Heterointerface Boosting Kinetics of Free‐Standing Na5V12O32 Cathode for Ultralong Lifespan Sodium‐Ion Batteries

X Song, X Li, H Shan, J Wang, W Li… - Advanced Functional …, 2024 - Wiley Online Library
The flexible free‐standing cathodes with high energy density have been challenging toward
wearable sodium‐ion batteries (SIBs). Herein, Na5V12O32 nanobelts (NVO‐NBs)‐based …

Cobalt‐free cathode materials: families and their prospects

H Zhao, WYA Lam, L Sheng, L Wang… - Advanced Energy …, 2022 - Wiley Online Library
With the rapid growth of global electro‐mobility, the demand for cobalt is rapidly increasing
because it is currently an indispensable component of the cathode materials in lithium‐ion …

An integrated surface coating strategy to enhance the electrochemical performance of nickel-rich layered cathodes

X Qu, H Huang, T Wan, L Hu, Z Yu, Y Liu, A Dou… - Nano Energy, 2022 - Elsevier
High-nickel layered oxides, LiNi x Co y Mn z O 2 (0.6≤ x< 1), are promising cathode
materials for producing batteries with high energy density and working voltage, while their …

A review on the stability and surface modification of layered transition-metal oxide cathodes

JM Kim, X Zhang, JG Zhang, A Manthiram, YS Meng… - Materials Today, 2021 - Elsevier
An ever-increasing market for electric vehicles (EVs), electronic devices and others has
brought tremendous attention on the need for high energy density batteries with reliable …

Pseudo‐bonding and electric‐field harmony for Li‐rich Mn‐based oxide cathode

J Chen, G Zou, W Deng, Z Huang, X Gao… - Advanced functional …, 2020 - Wiley Online Library
The practical application of Li‐rich Mn‐based oxide cathode is predominately retarded by
the capacity decline and voltage fading, associated with the structure distortion and anionic …

Inhibition of transition metals dissolution in cobalt-free cathode with ultrathin robust interphase in concentrated electrolyte

W Liu, J Li, W Li, H Xu, C Zhang, X Qiu - Nature Communications, 2020 - nature.com
The low Coulombic efficiency during cycling hinders the application of Cobalt-free lithium-
rich materials in lithium-ion batteries. Here we demonstrated that the dissolution of iron …