Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

Metal complexes containing a binuclear structural motif of the type MXM,(M, metal centers
and X, the bridging group), have emerged as an important area of research owing to the …

High-valent metal oxo complexes are prototypical intermediates for the activation and
hydroxylation of alkyl C–H bonds. Substituting the oxo ligand with other functional groups …

Transition metal–oxo complexes are key intermediates in a variety of oxidative
transformations, notably C–H bond activation. The relative rate of C–H bond activation …

[FeII (NCCH3)(NTB)](OTf) 2 (NTB= tris (2-benzimidazoylmethyl) amine, OTf=
trifluoromethanesulfonate) was reacted with difluoro (phenyl)-λ3-iodane (PhIF2) in the …

Recently, transition-metal terminal nonoxo complexes have shown a remarkable ability to
activate and functionalize C–H bonds via proton-coupled electron transfer (PCET). Here we …

The new nonheme iron complexes FeII (BNPAPh2O)(N3)(1), FeIII (BNPAPh2O)(OH)(N3)(2),
FeII (BNPAPh2O)(OH)(3), FeIII (BNPAPh2O)(OH)(NCS)(4), FeII (BNPAPh2O)(NCS)(5), FeIII …

We disclose a new reactivity mode for electrophilic cyano λ3‐iodanes as group transfer one‐
electron oxidants to synthesize FeIII and FeIV cyanide complexes. The inherent thermal …

Catalytic selective B–H functionalization of carboranes has recently attracted enormous
research interest, resulting in the development of a series of methods for transition metal …

While fluoride ions (F−) are abundant across environmental and biological systems,
common procedures and potentiometric sensors for quantifying aqueous F− are inefficient …