This review is the counterpart of a 2018 Chemical Reviews article (Adero, PO; Amarasekara,
H.; Wen, P.; Bohé, L.; Crich, D. Chem. Rev. 2018, 118, 8242–8284) that examined the …

A critical review of the state-of-the-art evidence in support of the mechanisms of
glycosylation reactions is provided. Factors affecting the stability of putative oxocarbenium …

Synthesis of oligosaccharides has, for the past couple of decades, been greatly improved by
new methods and the ongoing development of new technologies, such as automation in …

Anomerization, which involves cleavage and formation of the anomeric C–O bond, is of
fundamental importance in the carbohydrate chemistry. Herein, the unexpected gold (I) …

Carbohydrates play a significant role in numerous biological events, and the chemical
synthesis of carbohydrates is vital for further studies to understand their various biological …

The control of stereoselectivity in a glycosylation reaction remains one of the most
challenging aspects of oligosaccharide synthesis. Especially the synthesis of 1, 2‐cis …

Sulfoxides have emerged as pivotal constituents in modern carbohydrate chemistry. As
anomeric leaving groups, sulfinyl moieties may occupy positions directly at the anomeric …

The development of selectively protected monosaccharide building blocks that can reliably
be glycosylated with a wide variety of acceptors is expected to make oligosaccharide …

The development of a cation clock method based on the intramolecular Sakurai reaction for
probing the concentration dependence of the nucleophile in glycosylation reactions is …

The multifaceted biological importance of carbohydrates has made them very popular
targets in modern synthetic chemistry. Great progress has been made in stereoselective …