Metal–organic frameworks (MOFs) beyond crystallinity: amorphous MOFs, MOF liquids and MOF glasses
The field of metal–organic frameworks (MOFs) has been incorrectly believed to be purely
crystalline. However, non-crystalline MOFs (amorphous MOFs, MOF liquids, and MOF …
crystalline. However, non-crystalline MOFs (amorphous MOFs, MOF liquids, and MOF …
Confinement of luminescent guests in metal–organic frameworks: understanding pathways from synthesis and multimodal characterization to potential applications of …
This review gives an authoritative, critical, and accessible overview of an emergent class of
fluorescent materials termed “LG@ MOF”, engineered from the nanoscale confinement of …
fluorescent materials termed “LG@ MOF”, engineered from the nanoscale confinement of …
Metal–organic network-forming glasses
The crystal–liquid–glass phase transition of coordination polymers (CPs) and metal–organic
frameworks (MOFs) offers attractive opportunities as a new class of amorphous materials …
frameworks (MOFs) offers attractive opportunities as a new class of amorphous materials …
Highly Efficient and Direct Ultralong All‐Phosphorescence from Metal–Organic Framework Photonic Glasses
Realizing efficient and ultralong room‐temperature phosphorescence (RTP) is highly
desirable but remains a challenge due to the inherent competition between excited state …
desirable but remains a challenge due to the inherent competition between excited state …
Macroscopic Assembly of Chiral Hydrogen‐bonded Metal‐free Supramolecular Glasses for Enhanced Color‐tunable Ultralong Room Temperature Phosphorescence
F Nie, D Yan - Angewandte Chemie, 2023 - Wiley Online Library
Glassy materials, with desirable mechanical rigidity, sha** ability, high transparency, are
attracting great interest in diverse fields. However, optically bulk molecule‐based glasses …
attracting great interest in diverse fields. However, optically bulk molecule‐based glasses …
Metal‐organic framework glass anode with an exceptional cycling‐induced capacity enhancement for lithium‐ion batteries
Metal‐organic frameworks (MOFs) hold great promise as high‐energy anode materials for
next‐generation lithium‐ion batteries (LIBs) due to their tunable chemistry, pore structure …
next‐generation lithium‐ion batteries (LIBs) due to their tunable chemistry, pore structure …
Advancing the mechanical performance of glasses: perspectives and challenges
Glasses are materials that lack a crystalline microstructure and long‐range atomic order.
Instead, they feature heterogeneity and disorder on superstructural scales, which have …
Instead, they feature heterogeneity and disorder on superstructural scales, which have …
Metal–organic framework glass composites
The melting phenomenon in metal–organic frameworks (MOFs) has been recognised as
one of the fourth generation MOF paradigm behaviours. Molten MOFs have high …
one of the fourth generation MOF paradigm behaviours. Molten MOFs have high …
Interfacial Bonding between a Crystalline Metal–Organic Framework and an Inorganic Glass
The interface within a composite is critically important for the chemical and physical
properties of these materials. However, experimental structural studies of the interfacial …
properties of these materials. However, experimental structural studies of the interfacial …
Looking into the future of hybrid glasses
Glasses are typically formed by melt-quenching, that is, cooling of a liquid on a timescale
fast enough to avoid ordering to a crystalline state, and formerly thought to comprise three …
fast enough to avoid ordering to a crystalline state, and formerly thought to comprise three …