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Exploiting chemistry and molecular systems for quantum information science
The power of chemistry to prepare new molecules and materials has driven the quest for
new approaches to solve problems having global societal impact, such as in renewable …
new approaches to solve problems having global societal impact, such as in renewable …
Single-molecule magnets beyond a single lanthanide ion: the art of coupling
YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …
Understanding the unceasing evolution of Co (II) based single-ion magnets
Single-molecule magnets (SMMs) are molecules that exhibit energy barriers to spin
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …
A stable pentagonal bipyramidal Dy (III) single-ion magnet with a record magnetization reversal barrier over 1000 K
Single-molecule magnets (SMMs) with a large spin reversal barrier have been recognized to
exhibit slow magnetic relaxation that can lead to a magnetic hysteresis loop. Synthesis of …
exhibit slow magnetic relaxation that can lead to a magnetic hysteresis loop. Synthesis of …
Rare-earth based tetrapyrrolic sandwiches: chemistry, materials and applications
The unique properties of natural tetrapyrrolic compounds have inspired the rapid growth of
research interest in the design and synthesis of artificial porphyrinoids and their metal …
research interest in the design and synthesis of artificial porphyrinoids and their metal …
Record quantum tunneling time in an air-stable exchange-bias dysprosium macrocycle
Z Zhu, S Paul, C Zhao, J Wu, X Ying… - Journal of the …, 2024 - ACS Publications
In recent years, dysprosium macrocycle single-molecule magnets (SMMs) have received
increasing attention due to their excellent air/thermal stability, strong magnetic anisotropy …
increasing attention due to their excellent air/thermal stability, strong magnetic anisotropy …
Dipolar Coupling as a Mechanism for Fine Control of Magnetic States in ErCOT-Alkyl Molecular Magnets
The design of molecular magnets has progressed greatly by taking advantage of the ability
to impart successive perturbations and control vibronic transitions in 4f n systems through …
to impart successive perturbations and control vibronic transitions in 4f n systems through …
Giant coercivity and high magnetic blocking temperatures for N23− radical-bridged dilanthanide complexes upon ligand dissociation
Increasing the operating temperatures of single-molecule magnets—molecules that can
retain magnetic polarization in the absence of an applied field—has potential implications …
retain magnetic polarization in the absence of an applied field—has potential implications …
Lanthanide–radical single-molecule magnets: current status and future challenges
HD Li, SG Wu, ML Tong - Chemical Communications, 2023 - pubs.rsc.org
In the field of molecular magnetism, the lanthanide–radical (Ln–Rad) method has become
one of the most appealing tactics for introducing strong magnetic interactions and has …
one of the most appealing tactics for introducing strong magnetic interactions and has …
Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …
exchange and double exchange or spin crossover and valence tautomerism in small …