High‐entropy transparent ceramics: review of potential candidates and recently studied cases

G Zhang, Y Wu - International Journal of Applied Ceramic …, 2022 - Wiley Online Library
High‐entropy ceramics have been widely explored and extensively studied since the first
demonstration of the configuration entropy stabilized reversible transitions between multiple …

Perspectives on pyrochlores, defect fluorites, and related compounds: building blocks for chemical diversity and functionality

GR Lumpkin, RD Aughterson - Frontiers in Chemistry, 2021 - frontiersin.org
In this article we provide some perspectives on a range of pyrochlore and defect fluorite type
compounds with nominal A2B2O7, A2BO5, ABC2O7, and other stoichiometries. Typically …

Disorder in Ho 2 Ti 2− x Zr x O 7: pyrochlore to defect fluorite solid solution series

DL Drey, EC O'Quinn, T Subramani, K Lilova… - RSC …, 2020 - pubs.rsc.org
Pyrochlore (A2B2O7) is an important, isometric structure-type because of its large variety of
compositions and structural derivatives that are generally related to different disordering …

Lattice disorder and oxygen migration pathways in pyrochlore and defect-fluorite oxides

FP Marlton, ZM Zhang, YP Zhang, TE Proffen, CD Ling… - 2021 - journals.iucr.org
Pyrochlore oxides, with the general formula A2B2O7, are of considerable interest as
catalysts for the oxygen evolution reaction [1-5], where A2Ru2O7-δ pyrochlores have …

Long-and short-range orders in 10-component compositionally complex ceramics

D Zhang, Y Chen, H Vega, T Feng, D Yu… - Advanced Powder …, 2023 - Elsevier
Neutron diffraction and total scattering are combined to investigate a series of single-phase
10-component compositionally complex fluorite-based oxides,[(Pr 0.375 Nd 0.375 Yb 0.25) …

Emerging disorder in Gd 2 (Ti 1− x Zr x) 2 O 7 pyrochlores matrices for radioactive waste disposal: symmetry lowering versus defect clustering

A di Biase, C Castellano, G Confalonieri… - Journal of Materials …, 2023 - pubs.rsc.org
Pyrochlore compositions in the Gd2 (Ti1− xZrx) 2O7 solid solution have gained attention in
the field of radioactive waste forms because they are capable of withstanding high doses of …

New red-shade environmental-friendly multifunctional pigment based on Tb and Fe doped Y2Zr2O7 for ceramic applications and cool roof coatings

M Jovaní, A Sanz, H Beltrán-Mir, E Cordoncillo - Dyes and Pigments, 2016 - Elsevier
A new red-shade environmental friendly ceramic pigment with the general formula Y 2− x Tb
x Zr 2− y Fe y O 7− δ [x= 0, 0.25 and y= 0.15, 0.25, 0.35] was prepared by a polymeric sol-gel …

[HTML][HTML] Fabrication and characterization of high entropy pyrochlore ceramics

B Matović, D Zagorac, I Cvijović-Alagić… - boletín de la sociedad …, 2023 - Elsevier
High-entropy rare-earth (RE) zirconates with pyrochlore structure were successfully
fabricated by pressureless and spark plasma sintering. RE 2 Zr 2 O 7 compound with …

Effect of temperature on phase evolution in Gd2Zr2O7: a potential matrix for nuclear waste immobilization

M Jafar, SB Phapale, BP Mandal, M Roy… - Journal of Alloys and …, 2021 - Elsevier
The dependencies of phase evolution and thermodynamic properties of Gd 2 Zr 2 O 7 with
temperature of preparation have been reported. A series of samples with composition Gd 2 …

Preparation and Structure of Uranium-Incorporated Gd2Zr2O7 Compounds and Their Thermodynamic Stabilities under Oxidizing and Reducing Conditions

M Jafar, SB Phapale, BP Mandal, R Mishra… - Inorganic …, 2015 - ACS Publications
Gd2Zr2O7 is being contemplated as a futuristic matrix for the incorporation of high-level
radioactive nuclear waste. This compound has the unique ability to incorporate several …