Electronic defects in metal oxide photocatalysts

E Pastor, M Sachs, S Selim, JR Durrant… - Nature Reviews …, 2022 - nature.com
A deep understanding of defects is essential for the optimization of materials for solar energy
conversion. This is particularly true for metal oxide photo (electro) catalysts, which typically …

The kinetics of metal oxide photoanodes from charge generation to catalysis

S Corby, RR Rao, L Steier, JR Durrant - Nature Reviews Materials, 2021 - nature.com
Generating charge carriers with lifetimes long enough to drive catalysis is a critical aspect for
photoelectrochemical and photocatalytic systems, and a key determinant of their efficiency …

Mechanism for broadband white-light emission from two-dimensional (110) hybrid perovskites

T Hu, MD Smith, ER Dohner, MJ Sher… - The journal of …, 2016 - ACS Publications
The recently discovered phenomenon of broadband white-light emission at room
temperature in the (110) two-dimensional organic–inorganic perovskite (N-MEDA)[PbBr4](N …

Ultrafast electron dynamics in solar energy conversion

CS Ponseca Jr, P Chábera, J Uhlig, P Persson… - Chemical …, 2017 - ACS Publications
Electrons are the workhorses of solar energy conversion. Conversion of the energy of light to
electricity in photovoltaics, or to energy-rich molecules (solar fuel) through photocatalytic …

Femtosecond x-ray spectroscopy of an electrocyclic ring-opening reaction

AR Attar, A Bhattacherjee, CD Pemmaraju, K Schnorr… - Science, 2017 - science.org
The ultrafast light-activated electrocyclic ring-opening reaction of 1, 3-cyclohexadiene is a
fundamental prototype of photochemical pericyclic reactions. Generally, these reactions are …

Deciphering photoinduced catalytic reaction mechanisms in natural and artificial photosynthetic systems on multiple temporal and spatial scales using X-ray probes

LX Chen, J Yano - Chemical Reviews, 2024 - ACS Publications
Utilization of renewable energies for catalytically generating value-added chemicals is
highly desirable in this era of rising energy demands and climate change impacts. Artificial …

Excitation-wavelength-dependent small polaron trap** of photoexcited carriers in α-Fe2O3

LM Carneiro, SK Cushing, C Liu, Y Su, P Yang… - Nature materials, 2017 - nature.com
Small polaron formation is known to limit ground-state mobilities in metal oxide
photocatalysts. However, the role of small polaron formation in the photoexcited state and …

Photoinduced structural dynamics of molecular systems mapped by time-resolved X-ray methods

M Chergui, E Collet - Chemical reviews, 2017 - ACS Publications
We review the tremendous advances in ultrafast X-ray science, over the past 15 years,
making the best use of new ultrashort X-ray sources including table-top or large-scale …

[HTML][HTML] Charge migration and charge transfer in molecular systems

HJ Wörner, CA Arrell, N Banerji, A Cannizzo… - Structural …, 2017 - pubs.aip.org
The transfer of charge at the molecular level plays a fundamental role in many areas of
chemistry, physics, biology and materials science. Today, more than 60 years after the …

In situ observation of picosecond polaron self-localisation in α-Fe2O3 photoelectrochemical cells

E Pastor, JS Park, L Steier, S Kim, M Grätzel… - Nature …, 2019 - nature.com
Abstract Hematite (α-Fe2O3) is the most studied artificial oxygen-evolving photo-anode and
yet its efficiency limitations and their origin remain unknown. A sub-picosecond …