[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Magnetic anisotropy in two-to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism

AK Bar, C Pichon, JP Sutter - Coordination Chemistry Reviews, 2016 - Elsevier
This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …

A linear cobalt (II) complex with maximal orbital angular momentum from a non-Aufbau ground state

PC Bunting, M Atanasov, E Damgaard-Møller… - Science, 2018 - science.org
INTRODUCTION The magnetic properties of a single metal center are determined by a
combination of its total spin S and orbital angular momentum L. Orbital angular momentum …

Magnetic blocking in a linear iron(I) complex

JM Zadrozny, DJ ** analysis
H **ang, C Lee, HJ Koo, X Gong, MH Whangbo - Dalton Transactions, 2012 - pubs.rsc.org
The magnetic energy levels of a given magnetic solid are closely packed in energy because
the interactions between magnetic ions are weak. Thus, in describing its magnetic …

Slow magnetic relaxation in a high-spin iron (II) complex

DE Freedman, WH Harman, TD Harris… - Journal of the …, 2010 - ACS Publications
Slow magnetic relaxation is observed for [(tpaMes) Fe]−, a trigonal pyramidal complex of
high-spin iron (II), providing the first example of a mononuclear transition metal complex that …

Role of Coordination Number and Geometry in Controlling the Magnetic Anisotropy in FeII, CoII, and NiII Single‐Ion Magnets

A Sarkar, S Dey, G Rajaraman - Chemistry–A European …, 2020 - Wiley Online Library
Since the last decade, the focus in the area of single‐molecule magnets (SMMs) has been
shifting constructively towards the development of single‐ion magnets (SIMs) based on …

A Heterometallic FeII–DyIII Single‐Molecule Magnet with a Record Anisotropy Barrier

JL Liu, JY Wu, YC Chen, V Mereacre… - Angewandte Chemie …, 2014 - Wiley Online Library
A record anisotropy barrier (319 cm− 1) for all d‐f complexes was observed for a unique FeII‐
DyIII‐FeII single‐molecule magnet (SMM), which possesses two asymmetric and distorted …

Slow magnetic relaxation in a family of trigonal pyramidal iron (II) pyrrolide complexes

WH Harman, TD Harris, DE Freedman… - Journal of the …, 2010 - ACS Publications
We present a family of trigonal pyramidal iron (II) complexes supported by tris (pyrrolyl-α-
methyl) amine ligands of the general formula [M (solv) n][(tpaR) Fe](M= Na, R= tert-butyl (1) …