The golden age of transfer hydrogenation
D Wang, D Astruc - Chemical reviews, 2015 - ACS Publications
Hydrogenation is one of the most fundamental transformations in organic synthesis, and its
industrial applications span from fine chemicals to pharmaceuticals synthesis. 1− 3 Direct …
industrial applications span from fine chemicals to pharmaceuticals synthesis. 1− 3 Direct …
The role of the metal-bound N–H functionality in Noyori-type molecular catalysts
PA Dub, JC Gordon - Nature Reviews Chemistry, 2018 - nature.com
Noyori-type catalysts have found numerous applications in research and industrial settings.
The central mechanistic component of such catalysts is a metal centre coordinated to a N–H …
The central mechanistic component of such catalysts is a metal centre coordinated to a N–H …
Metal–ligand bifunctional catalysis: the “accepted” mechanism, the issue of concertedness, and the function of the ligand in catalytic cycles involving hydrogen atoms
For years, following the ideas of Shvo and Noyori, the core assumption of metal–ligand
bifunctional molecular catalysis has relied on the direct involvement of the chelating ligand …
bifunctional molecular catalysis has relied on the direct involvement of the chelating ligand …
The mechanism of enantioselective ketone reduction with Noyori and Noyori–Ikariya bifunctional catalysts
The catalytic hydrogenation of prochiral ketones with second and third-row transition metal
complexes bearing chelating chiral ligands containing at least one N–H functionality has …
complexes bearing chelating chiral ligands containing at least one N–H functionality has …
Broader, greener, and more efficient: Recent advances in asymmetric transfer hydrogenation
Asymmetric transfer hydrogenation has become a practically useful tool in reduction
chemistry in the last decade or so. This was largely triggered by the seminal work of Noyori …
chemistry in the last decade or so. This was largely triggered by the seminal work of Noyori …
Why does alkylation of the N–H functionality within M/NH bifunctional Noyori-type catalysts lead to turnover?
Molecular metal/NH bifunctional Noyori-type catalysts are remarkable in that they are among
the most efficient artificial catalysts developed to date for the hydrogenation of carbonyl …
the most efficient artificial catalysts developed to date for the hydrogenation of carbonyl …
Recent advances in metal catalysts with hybrid ligands
WH Zhang, SW Chien, TSA Hor - Coordination Chemistry Reviews, 2011 - Elsevier
Recent advances in metal catalysts with hybrid ligands - ScienceDirect Skip to main contentSkip
to article Elsevier logo Journals & Books Search RegisterSign in View PDF Download full …
to article Elsevier logo Journals & Books Search RegisterSign in View PDF Download full …
A Stable Anionic N-heterocyclic carbene and its zwitterionic complexes
V César, N Lugan, G Lavigne - Journal of the American Chemical …, 2008 - ACS Publications
Pyrimidinium betaïnes (1), readily accessible via a straightforward modular synthesis from a
formamidine and a monosubstituted malonic acid, are readily deprotonated by n BuLi (or …
formamidine and a monosubstituted malonic acid, are readily deprotonated by n BuLi (or …
Transfer Hydrogenation of Nitriles, Olefins, and N-Heterocycles Catalyzed by an N-Heterocyclic Carbene-Supported Half-Sandwich Complex of Ruthenium
VH Mai, GI Nikonov - Organometallics, 2016 - ACS Publications
In the presence of KOBut, N-heterocyclic carbene-supported half-sandwich complex [Cp
(IPr) Ru (pyr) 2][PF6](3)(IPr= 1, 3-bis (2, 6-diisopropylphenyl) imidazol-2-ylidene) catalyzes …
(IPr) Ru (pyr) 2][PF6](3)(IPr= 1, 3-bis (2, 6-diisopropylphenyl) imidazol-2-ylidene) catalyzes …
Chiral (η6-p-Cymene)ruthenium(II) Complexes Containing Monodentate Acylthiourea Ligands for Efficient Asymmetric Transfer Hydrogenation of Ketones
MM Sheeba, M Muthu Tamizh, LJ Farrugia… - …, 2014 - ACS Publications
The new chiral ligands (R)-/(S)-N-((1-phenylethyl) carbamothioyl) benzamide (L1/L2),(R)-
/(S)-N-((1-phenylethyl) carbamothioyl) thiophene-2-carboxamide (L3/L4), and (R)-/(S)-N-((1 …
/(S)-N-((1-phenylethyl) carbamothioyl) thiophene-2-carboxamide (L3/L4), and (R)-/(S)-N-((1 …