Selective hydrogenation over supported metal catalysts: from nanoparticles to single atoms

L Zhang, M Zhou, A Wang, T Zhang - Chemical reviews, 2019 - ACS Publications
Selective catalytic hydrogenation has wide applications in both petrochemical and fine
chemical industries, however, it remains challenging when two or multiple functional groups …

[HTML][HTML] Magic of hydrogen spillover: Understanding and application

H Shen, H Li, Z Yang, C Li - Green Energy & Environment, 2022 - Elsevier
The hydrogen spillover effect (HSPE) plays an important role in heterogeneous catalysis
and hydrogen storage as an interfacial phenomenon, which facilitates the improvement of …

Unprecedentedly high activity and selectivity for hydrogenation of nitroarenes with single atomic Co1-N3P1 sites

H **, P Li, P Cui, J Shi, W Zhou, X Yu, W Song… - Nature …, 2022 - nature.com
Transition metal single atom catalysts (SACs) with M1-Nx coordination configuration have
shown outstanding activity and selectivity for hydrogenation of nitroarenes. Modulating the …

Spillover in heterogeneous catalysis: new insights and opportunities

M **ong, Z Gao, Y Qin - ACS Catalysis, 2021 - ACS Publications
Spillover is a well-known phenomenon in heterogeneous catalysis and is involved in many
important reactions. The establishment of the spillover concept opened up a new research …

Catalyst support effects on hydrogen spillover

W Karim, C Spreafico, A Kleibert, J Gobrecht… - Nature, 2017 - nature.com
Hydrogen spillover is the surface migration of activated hydrogen atoms from a metal
catalyst particle, on which they are generated, onto the catalyst support. The phenomenon …

Enabling long-distance hydrogen spillover in nonreducible metal-organic frameworks for catalytic reaction

XJ Bai, C Yang, Z Tang - Nature Communications, 2024 - nature.com
Hydrogen spillover is an extraordinary effect in heterogeneous catalysis and hydrogen
storage, which refers to the surface migration of metal particle-activated hydrogen atoms …

Structure–relaxivity relationships of magnetic nanoparticles for magnetic resonance imaging

Z Zhou, L Yang, J Gao, X Chen - Advanced Materials, 2019 - Wiley Online Library
Magnetic nanoparticles (MNPs) have been extensively explored as magnetic resonance
imaging (MRI) contrast agents. With the increasing complexity in the structure of modern …

Iron oxide surfaces

GS Parkinson - Surface Science Reports, 2016 - Elsevier
The current status of knowledge regarding the surfaces of the iron oxides, magnetite (Fe 3 O
4), maghemite (γ-Fe 2 O 3), haematite (α-Fe 2 O 3), and wüstite (Fe 1− x O) is reviewed. The …

Water-assisted hydrogen spillover in Pt nanoparticle-based metal–organic framework composites

Z Gu, M Li, C Chen, X Zhang, C Luo, Y Yin… - Nature …, 2023 - nature.com
Hydrogen spillover is the migration of activated hydrogen atoms from a metal particle onto
the surface of catalyst support, which has made significant progress in heterogeneous …

Interfacial effects in iron-nickel hydroxide–platinum nanoparticles enhance catalytic oxidation

G Chen, Y Zhao, G Fu, PN Duchesne, L Gu, Y Zheng… - Science, 2014 - science.org
Hybrid metal nanoparticles can allow separate reaction steps to occur in close proximity at
different metal sites and accelerate catalysis. We synthesized iron-nickel hydroxide …