Dynamic and reconfigurable materials from reversible network interactions

MJ Webber, MW Tibbitt - Nature Reviews Materials, 2022 - nature.com
Polymer materials provide solutions to some of the most pressing environmental,
manufacturing and health-care challenges. Traditional thermoplastic and thermoset …

Structurally dynamic hydrogels for biomedical applications: pursuing a fine balance between macroscopic stability and microscopic dynamics

K Zhang, Q Feng, Z Fang, L Gu, L Bian - Chemical Reviews, 2021 - ACS Publications
Owing to their unique chemical and physical properties, hydrogels are attracting increasing
attention in both basic and translational biomedical studies. Although the classical hydrogels …

Strategies and molecular design criteria for 3D printable hydrogels

T Jungst, W Smolan, K Schacht, T Scheibel… - Chemical …, 2016 - ACS Publications
Additive manufacturing (AM), also referred to as rapid prototy**, solid free-form fabrication,
or simply threedimensional (3D) printing, comprises a number of technologies that allow the …

Polymer engineering based on reversible covalent chemistry: A promising innovative pathway towards new materials and new functionalities

ZP Zhang, MZ Rong, MQ Zhang - Progress in Polymer Science, 2018 - Elsevier
Reversible covalent polymers are able to change their bond arrangement and structure via
reversible reaction triggered by external stimuli including heating, light and pH, while …

Activated ester containing polymers: opportunities and challenges for the design of functional macromolecules

A Das, P Theato - Chemical reviews, 2016 - ACS Publications
Rapidly growing demand of functional polymers in various interdisciplinary areas of
research has accentuated the need for modern synthetic tools to develop advanced …

Self‐healing in supramolecular polymers

A Campanella, D Döhler… - Macromolecular rapid …, 2018 - Wiley Online Library
Adaption and self‐healing are two major principles in material science, often coupled with
the placement of supramolecular moieties within a material. Proper molecular design can …

The influence of hydrogen bonding side-groups on viscoelastic behavior of linear and network polymers

CL Lewis, K Stewart, M Anthamatten - Macromolecules, 2014 - ACS Publications
Polymers containing hydrogen-bonding side groups (HBGs) can form transient
supramolecular networks that exhibit technologically useful viscoelastic properties. Here, we …

Connecting supramolecular bond lifetime and network mobility for scratch healing in poly (butyl acrylate) ionomers containing sodium, zinc and cobalt

RK Bose, N Hohlbein, SJ Garcia, AM Schmidt… - Physical Chemistry …, 2015 - pubs.rsc.org
In this work, we correlate network dynamics, supramolecular reversibility and the
macroscopic surface scratch healing behavior for a series of elastomeric ionomers based on …

Anomalous self-diffusion and sticky Rouse dynamics in associative protein hydrogels

S Tang, M Wang, BD Olsen - Journal of the American Chemical …, 2015 - ACS Publications
Natural and synthetic materials based on associating polymers possess diverse mechanical
behavior, transport properties and responsiveness to external stimuli. Although much is …

Engineering elasticity and relaxation time in metal-coordinate cross-linked hydrogels

SC Grindy, M Lenz, N Holten-Andersen - Macromolecules, 2016 - ACS Publications
Reversible cross-links between polymer chains are a promising avenue to engineer the
mechanical properties of soft materials and in particular hydrogels. Such developments are …