Metal–ligand cooperation, in which both the metal and the ligand of a transition metal
complex actively participate in chemical transformations leading to enhanced reactivity or …

Organocatalysis has captured the imagination of a significant group of synthetic chemists.
Much of the mechanistic understanding of these reactions has come from computational …

Chiral allenes are important structural motifs frequently found in natural products,
pharmaceuticals, and other organic compounds. Asymmetric 1, 4-difunctionalization of 1, 3 …

The different enantiomers of specific chiral molecules frequently exhibit disparate biological,
physiological, or pharmacological properties. Therefore, the efficient synthesis of single …

Many reactions involving allenyl ion species have been studied, but reactions involving
allenyl radicals are less well understood, perhaps because of the inconvenience associated …

The development of general and efficient strategies for the construction of allenes is
important due to their wide applications. Although few protocols have been developed via …

Allenes have proven themselves to be valuable building blocks toward complex molecular
targets, revealing novel applications in natural product synthesis, pharmaceutical chemistry …

Allene moieties with axial chirality are featured in many natural products with biological
activities. They also serve as unique building blocks in organic synthesis and as chiral …

Although chiral allene preparation via formal SN2'nucleophilic substitutions of
enantioenriched propargylic derivatives or metal-catalyzed reactions of racemic propargylic …

While one-carbon central chirality of organic molecules has been recognized and
extensively studied for more than a century, far less attention has been paid to three-carbon …