Gold complexes have emerged as the catalysts of choice for various functionalization
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …

Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Often stoichiometric amounts of gold find use in materials science; occasionally gold is even
used as a support. This review discusses the contributions of gold catalysis, both …

For a while, the reactivity of gold complexes was largely dominated by their Lewis acid
behavior. In contrast to the other transition metals, the elementary steps of organometallic …

Herein, we report a gold-catalyzed Heck reaction facilitated by the ligand-enabled Au (I)/Au
(III) redox catalysis. The elementary organometallic steps such as migratory insertion and β …

This Review showcases the ability of bi‐and tridentate ligands to stabilize gold in high
oxidation states through the formation of mono‐and biscyclometalated gold (III) complexes …

The successful realization of gold‐catalyzed chain‐walking reactions, facilitated by ligand‐
enabled Au (I)/Au (III) redox catalysis, has been reported for the first time. This breakthrough …

Seit langem war die Reaktivität von Goldkomplexen überwiegend durch ihre Eigenschaft als
Lewis‐Säure bestimmt. Im Unterschied zu anderen Übergangsmetallen wurden …

Exploration of elementary reactions in organometallic catalysis is an important method with
which to discover new reactions. In this article, we report a gold (I)‐catalyzed iodo …

A MeDalPhos-ligated gold (III) metallafluorene complex, generated via C–C oxidative
addition of biphenylene, reacts with CO to produce 9-fluorenone. Experimental and …