Oxidation is one of the fundamental transformations in organic synthesis. The selective
oxidation of inert substrates is interesting and important. In this review, the transition metal …

The synthesis of transition‐metal and rare‐earth clusters has become a very active research
field, mainly because these compounds can behave as molecule‐based magnets. The …

This Perspective summarises the chemistry of the pyrazole ring, and reviews the metal
coordination modes adopted by 1H-pyrazoles and their anions. Pyrazolide anions are …

Two new trinuclear copper (II) complexes,[Cu3 (μ3-OH)(daat)(Hdat) 2 (ClO4) 2 (H2O)
3](ClO4) 2· 2H2O (1) and [Cu3 (μ3-OH)(aaat) 3 (H2O) 3](ClO4) 2· 3H2O (2)(daat= 3, 5 …

To investigate the influence of organic molecules with reactive functional groups as
templates on the structures of the resulting MOFs, four novel complexes based on the pyridyl …

The preparation, characterization, and optimization of the functional properties of mono‐and
polynuclear coordination complexes containing heteroaromatic nitrogen ligands are …

Nanojars are large (2 nm wide) anion-incarcerating coordination complexes of the
composition [anion⊂{Cu (μ-OH)(μ-pz)} n](n= 27–36), formed by the self-assembly of simple …

The design and synthesis of high-dimensional materials based on secondary building
blocks (SBUs) play a pivotal role in the further development of functional molecular …

Inverse coordination is the formation of metal complexes in which the acceptor and donor
sites are reversed compared to classical coordination complexes. In the inverse …

Nanojars are a class of supramolecular anion-incarcerating coordination complexes that self-
assemble from Cu2+ ions, pyrazole, and a strong base in the presence of highly hydrophilic …