Rare earth starting materials and methodologies for synthetic chemistry
F Ortu - Chemical Reviews, 2022 - ACS Publications
The number of rare earth (RE) starting materials used in synthesis is staggering, ranging
from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl …
from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl …
Mono (cyclopentadienyl) complexes of the rare-earth metals
S Arndt, J Okuda - Chemical reviews, 2002 - ACS Publications
Organometallic complexes of the rare-earth metals are conventionally supported by bis
(cyclopentadienyl) ligand frameworks, 1-8 in particular if such complexes are used as …
(cyclopentadienyl) ligand frameworks, 1-8 in particular if such complexes are used as …
A rare-earth metal retrospective to stimulate all fields
Formulating insightful questions and experiments is crucial to the advancement of science.
The purpose of this Perspective is to encourage scientists in all areas of chemistry to ask …
The purpose of this Perspective is to encourage scientists in all areas of chemistry to ask …
Recent developments in organolanthanide polymerization catalysts
Z Hou, Y Wakatsuki - Coordination Chemistry Reviews, 2002 - Elsevier
This review describes recent advances in the synthesis and polymerization chemistry of
organolanthanide complexes (including those of scandium and yttrium), with emphasis …
organolanthanide complexes (including those of scandium and yttrium), with emphasis …
Cationic organometallic complexes of scandium, yttrium, and the lanthanoids
PM Zeimentz, S Arndt, BR Elvidge, J Okuda - Chemical reviews, 2006 - ACS Publications
The organometallic chemistry of the rare-earth metals (the term “rare-earth metal” in this
article will include scandium and yttrium alongside the elements from lanthanum to lutetium …
article will include scandium and yttrium alongside the elements from lanthanum to lutetium …
Homoleptic rare-earth metal complexes containing Ln− C σ-bonds
M Zimmermann, R Anwander - Chemical reviews, 2010 - ACS Publications
The past decade has witnessed an enormous growth in the chemistry of σ-bonded rare-
earth metal (Ln) alkyls, particularly due to their relevance for Ziegler-type anionic …
earth metal (Ln) alkyls, particularly due to their relevance for Ziegler-type anionic …
Organolathanide-catalyzed regioselective intermolecular hydroamination of alkenes, alkynes, vinylarenes, di-and trivinylarenes, and methylenecyclopropanes. Scope …
JS Ryu, GY Li, TJ Marks - Journal of the American Chemical …, 2003 - ACS Publications
Organolanthanide complexes of the type Cp '2LnCH (SiMe3) 2 (Cp '= η5-Me5C5; Ln= La,
Nd, Sm, Lu) and Me2SiCp ''2LnCH (SiMe3) 2 (Cp ''= η5-Me4C5; Ln= Nd, Sm, Lu) serve as …
Nd, Sm, Lu) and Me2SiCp ''2LnCH (SiMe3) 2 (Cp ''= η5-Me4C5; Ln= Nd, Sm, Lu) serve as …
Recent advances in organoactinide chemistry as exemplified by cyclopentadienyl compounds
M Ephritikhine - Organometallics, 2013 - ACS Publications
The ubiquity of the cyclopentadienyl ligand permits us to use its complexes as
representative examples for the description of recent highlights in organometallic and more …
representative examples for the description of recent highlights in organometallic and more …
Intramolecular hydrophosphination/cyclization of phosphinoalkenes and phosphinoalkynes catalyzed by organolanthanides: scope, selectivity, and mechanism
MR Douglass, CL Stern, TJ Marks - Journal of the American …, 2001 - ACS Publications
Organolanthanide complexes of the general type Cp '2LnE (TMS) 2 (Cp '= η5-Me5C5; Ln=
La, Sm, Y, Lu; E= CH, N; TMS= SiMe3) serve as effective precatalysts for the rapid …
La, Sm, Y, Lu; E= CH, N; TMS= SiMe3) serve as effective precatalysts for the rapid …
Recent advances in organothorium and organouranium catalysis
T Andrea, MS Eisen - Chemical Society Reviews, 2008 - pubs.rsc.org
In this critical review we summarize the latest results obtained during the last decade
concerning the catalytic activities of organoactinide complexes. We begin with a brief …
concerning the catalytic activities of organoactinide complexes. We begin with a brief …