Rare earth starting materials and methodologies for synthetic chemistry

F Ortu - Chemical Reviews, 2022 - ACS Publications
The number of rare earth (RE) starting materials used in synthesis is staggering, ranging
from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl …

Mono (cyclopentadienyl) complexes of the rare-earth metals

S Arndt, J Okuda - Chemical reviews, 2002 - ACS Publications
Organometallic complexes of the rare-earth metals are conventionally supported by bis
(cyclopentadienyl) ligand frameworks, 1-8 in particular if such complexes are used as …

A rare-earth metal retrospective to stimulate all fields

JC Wedal, WJ Evans - Journal of the American Chemical Society, 2021 - ACS Publications
Formulating insightful questions and experiments is crucial to the advancement of science.
The purpose of this Perspective is to encourage scientists in all areas of chemistry to ask …

Recent developments in organolanthanide polymerization catalysts

Z Hou, Y Wakatsuki - Coordination Chemistry Reviews, 2002 - Elsevier
This review describes recent advances in the synthesis and polymerization chemistry of
organolanthanide complexes (including those of scandium and yttrium), with emphasis …

Cationic organometallic complexes of scandium, yttrium, and the lanthanoids

PM Zeimentz, S Arndt, BR Elvidge, J Okuda - Chemical reviews, 2006 - ACS Publications
The organometallic chemistry of the rare-earth metals (the term “rare-earth metal” in this
article will include scandium and yttrium alongside the elements from lanthanum to lutetium …

Homoleptic rare-earth metal complexes containing Ln− C σ-bonds

M Zimmermann, R Anwander - Chemical reviews, 2010 - ACS Publications
The past decade has witnessed an enormous growth in the chemistry of σ-bonded rare-
earth metal (Ln) alkyls, particularly due to their relevance for Ziegler-type anionic …

Organolathanide-catalyzed regioselective intermolecular hydroamination of alkenes, alkynes, vinylarenes, di-and trivinylarenes, and methylenecyclopropanes. Scope …

JS Ryu, GY Li, TJ Marks - Journal of the American Chemical …, 2003 - ACS Publications
Organolanthanide complexes of the type Cp '2LnCH (SiMe3) 2 (Cp '= η5-Me5C5; Ln= La,
Nd, Sm, Lu) and Me2SiCp ''2LnCH (SiMe3) 2 (Cp ''= η5-Me4C5; Ln= Nd, Sm, Lu) serve as …

Recent advances in organoactinide chemistry as exemplified by cyclopentadienyl compounds

M Ephritikhine - Organometallics, 2013 - ACS Publications
The ubiquity of the cyclopentadienyl ligand permits us to use its complexes as
representative examples for the description of recent highlights in organometallic and more …

Intramolecular hydrophosphination/cyclization of phosphinoalkenes and phosphinoalkynes catalyzed by organolanthanides: scope, selectivity, and mechanism

MR Douglass, CL Stern, TJ Marks - Journal of the American …, 2001 - ACS Publications
Organolanthanide complexes of the general type Cp '2LnE (TMS) 2 (Cp '= η5-Me5C5; Ln=
La, Sm, Y, Lu; E= CH, N; TMS= SiMe3) serve as effective precatalysts for the rapid …

Recent advances in organothorium and organouranium catalysis

T Andrea, MS Eisen - Chemical Society Reviews, 2008 - pubs.rsc.org
In this critical review we summarize the latest results obtained during the last decade
concerning the catalytic activities of organoactinide complexes. We begin with a brief …