Knotting matters: orderly molecular entanglements

Z Ashbridge, SDP Fielden, DA Leigh, L Pirvu… - Chemical Society …, 2022 - pubs.rsc.org
Entangling strands in a well-ordered manner can produce useful effects, from shoelaces and
fishing nets to brown paper packages tied up with strings. At the nanoscale, non-crystalline …

Molecular knots

SDP Fielden, DA Leigh… - Angewandte Chemie …, 2017 - Wiley Online Library
The first synthetic molecular trefoil knot was prepared in the late 1980s. However, it is only in
the last few years that more complex small‐molecule knot topologies have been realized …

On virus growth and form

R Zandi, B Dragnea, A Travesset, R Podgornik - Physics Reports, 2020 - Elsevier
We review approaches aimed at deciphering the physical mechanisms responsible for viral
structure and assembly. We discuss the basic principles of condensed matter physics …

Quantum-inspired encoding enhances stochastic sampling of soft matter systems

F Slongo, P Hauke, P Faccioli, C Micheletti - Science Advances, 2023 - science.org
Quantum advantage in solving physical problems is still hard to assess due to hardware
limitations. However, algorithms designed for quantum computers may engender …

From a melt of rings to chromosome territories: the role of topological constraints in genome folding

JD Halverson, J Smrek, K Kremer… - Reports on Progress in …, 2014 - iopscience.iop.org
We review pro and contra of the hypothesis that generic polymer properties of topological
constraints are behind many aspects of chromatin folding in eukaryotic cells. For that …

Template synthesis of molecular knots

JF Ayme, JE Beves, CJ Campbell… - Chemical Society Reviews, 2013 - pubs.rsc.org
This tutorial review outlines the different template strategies that chemists have employed to
synthesise knotted molecular topologies. Metal ion coordination, hydrogen bonding and …

Activity-induced collapse and arrest of active polymer rings

E Locatelli, V Bianco, P Malgaretti - Physical Review Letters, 2021 - APS
We investigate, using numerical simulations, the conformations of isolated active ring
polymers. We find that their behavior depends crucially on their size: Short rings (N≲ 100) …

50th Anniversary Perspective: Polymer ConformationA Pedagogical Review

ZG Wang - Macromolecules, 2017 - ACS Publications
The study of the conformation properties of macromolecules is at the heart of polymer
science. Essentially all physical properties of polymers are manifestations of the underlying …

Stereoselective synthesis of a composite knot with nine crossings

L Zhang, AJ Stephens, AL Nussbaumer… - Nature Chemistry, 2018 - nature.com
The simultaneous synthesis of a molecular nine-crossing composite knot that contains three
trefoil tangles of the same handedness and a 9 7 3 link (a type of cyclic [3] catenane …

Activity-driven polymer knotting for macromolecular topology engineering

JX Li, S Wu, LL Hao, QL Lei, YQ Ma - Science Advances, 2024 - science.org
Macromolecules can gain special properties by adopting knotted conformations, but
engineering knotted macromolecules is a challenging task. Here, we unexpectedly find that …