Electric field poled organic electro-optic materials: state of the art and future prospects

LR Dalton, PA Sullivan, DH Bale - Chemical reviews, 2010 - ACS Publications
Information is created, processed, transported, and detected using electrons, photons,
phonons, or plasmons. Of these basic components of information technology, utilization of …

Optimizing calculations of electronic excitations and relative hyperpolarizabilities of electrooptic chromophores

LE Johnson, LR Dalton… - Accounts of Chemical …, 2014 - ACS Publications
Conspectus Organic glasses containing chromophores with large first hyperpolarizabilities
(β) are promising for compact, high-bandwidth, and energy-efficient electro-optic devices …

Optical chirality and its interaction with matter

Y Tang, AE Cohen - Physical review letters, 2010 - APS
We introduce a measure of the local density of chirality of the electromagnetic field. This
optical chirality determines the asymmetry in the rates of excitation between a small chiral …

Ultrahigh electro-optic coefficients, high index of refraction, and long-term stability from Diels–Alder cross-linkable binary molecular glasses

H Xu, F Liu, DL Elder, LE Johnson… - Chemistry of …, 2020 - ACS Publications
The development of organic electro-optic (EO) materials that concurrently possess a high
electro-optic coefficient (r 33), high index of refraction, and long-term or high-temperature …

Benchmark study of the linear and nonlinear optical polarizabilities in proto-type NLO molecule of para-nitroaniline

S Muhammad, RA Shehzad, J Iqbal… - Journal of Theoretical …, 2019 - World Scientific
In the present investigation, for the first time, we have performed a thorough study about
different functionals and basis sets for linear and nonlinear optical (NLO) properties of para …

Rational Enhancement of Second-Order Nonlinearity: Bis-(4-methoxyphenyl)hetero-aryl-amino Donor-Based Chromophores: Design, Synthesis, and Electrooptic …

JA Davies, A Elangovan, PA Sullivan… - Journal of the …, 2008 - ACS Publications
Two new highly hyperpolarizable chromophores, based on N, N-bis-(4-methoxyphenyl) aryl-
amino donors and phenyl-trifluoromethyl-tricyanofuran (CF 3-Ph-TCF) acceptor linked …

[HTML][HTML] Perspective: Nanophotonic electro-optics enabling THz bandwidths, exceptional modulation and energy efficiencies, and compact device footprints

LR Dalton, J Leuthold, BH Robinson, C Haffner… - APL Materials, 2023 - pubs.aip.org
The growth of integrated photonics has driven the need for efficient, high-bandwidth
electrical-to-optical (EO) signal conversion over a broad range of frequencies (MHz–THz) …

Applicability of hybrid density functional theory methods to calculation of molecular hyperpolarizability

KY Suponitsky, S Tafur, AE Masunov - The Journal of chemical physics, 2008 - pubs.aip.org
The donor/acceptor (D/A) substituted π-conjugated organic molecules possess extremely
fast nonlinear optical (NLO) response time that is purely electronic in origin. This makes …

Theory-inspired development of organic electro-optic materials

PA Sullivan, LR Dalton - Accounts of Chemical Research, 2010 - ACS Publications
Correlated time-dependent density functional theory (TDDFT) quantum mechanical and
pseudo-atomistic Monte Carlo (PAMC) statistical mechanical methods have been used to …

Optimum exchange for calculation of excitation energies and hyperpolarizabilities of organic electro-optic chromophores

K Garrett, XA Sosa Vazquez, SB Egri… - Journal of Chemical …, 2014 - ACS Publications
Organic electro-optic (OEO) materials integrated into silicon–organic hybrid devices afford
significant improvements in size, weight, power, and bandwidth performance of integrated …