Role of Coordination Number and Geometry in Controlling the Magnetic Anisotropy in FeII, CoII, and NiII Single‐Ion Magnets
Since the last decade, the focus in the area of single‐molecule magnets (SMMs) has been
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
Large easy-axis magnetic anisotropy in a series of trigonal prismatic mononuclear cobalt (II) complexes with zero-field hidden single-molecule magnet behaviour: the …
A Landart-Gereka, MM Quesada-Moreno… - Inorganic Chemistry …, 2022 - pubs.rsc.org
The complexes [Co (L)] X· S (X= CoCl42−, S= CH3CN (1); X= ZnCl42−, S= CH3OH (2)),[Co
(L)] X2· S (X= ClO4−, S= 2CH3OH (3) and X= BF4−(4)) and [Co (L)(NCS) 2](5), where L= the …
(L)] X2· S (X= ClO4−, S= 2CH3OH (3) and X= BF4−(4)) and [Co (L)(NCS) 2](5), where L= the …
Hydrogen-bonded framework of a cobalt (II) complex showing superior stability and field-induced slow magnetic relaxation
A unique hydrogen-bonded organic–inorganic framework (HOIF) constructed from a
mononuclear cobalt (II) complex,[Co (MCA) 2·(H2O) 2](HMCA= 4-imidazolecarboxylic acid) …
mononuclear cobalt (II) complex,[Co (MCA) 2·(H2O) 2](HMCA= 4-imidazolecarboxylic acid) …
Field-induced slow magnetic relaxation behaviours in binuclear cobalt (ii) metallocycles and exchange-coupled clusters
Precise control of the structures and magnetic properties of a molecular material constitutes
an important challenge to realize tailor-made magnetic function. Herein, we report that the …
an important challenge to realize tailor-made magnetic function. Herein, we report that the …
Incorporating highly anisotropic four-coordinate Co (II) ions within one-dimensional coordination chains
Low-coordinate metallic ions have been well recognized for constructing good-performance
single ion magnets (SIMs) due to their enhanced magnetic anisotropy; however, the …
single ion magnets (SIMs) due to their enhanced magnetic anisotropy; however, the …
Tuning the structure and magnetic properties via distinct pyridine derivatives in cobalt (II) coordination polymers
Precise modulation of the structure and magnetic properties of coordination compounds is of
great importance in the development of framework magnetic materials. Herein, we report …
great importance in the development of framework magnetic materials. Herein, we report …
Low symmetry aspects in electron magnetic resonance (EMR) and optical spectroscopy of coordination compounds of transition ions: Crucial notions and issues …
EMR and optical spectroscopy are important techniques enabling characterization of
transition 3d/4f ions in coordination compounds, which often exhibit low symmetry sites. Low …
transition 3d/4f ions in coordination compounds, which often exhibit low symmetry sites. Low …
A porous cobalt (II)–organic framework exhibiting high room temperature proton conductivity and field-induced slow magnetic relaxation
A two-dimensional (2D) cobalt (II) metal–organic framework (MOF) constructed by a ditopic
organic ligand, formulated as {[Co (Hbic)(H2O)]· 4H2O} n (1)(H2bic= 1H-benzimidazole-5 …
organic ligand, formulated as {[Co (Hbic)(H2O)]· 4H2O} n (1)(H2bic= 1H-benzimidazole-5 …
Tuning chain topologies and magnetic anisotropy in one-dimensional cobalt (II) coordination polymers via distinct dicarboxylates
Based on a terpyridine derivative and two different dicarboxylate ligands, two new cobalt (II)
coordination polymers, namely [Co (pytpy)(DClbdc)] n (1) and [Co (pytpy)(ndc)] n (2)(pytpy …
coordination polymers, namely [Co (pytpy)(DClbdc)] n (1) and [Co (pytpy)(ndc)] n (2)(pytpy …
Structure-property correlation in stabilizing axial magnetic anisotropy in octahedral Co (II) complexes
Stabilizing an easy axis of magnetization in an octahedral Co (II) complex is an extremely
challenging task, which is evident from reports that more than 90% possess easy-plane …
challenging task, which is evident from reports that more than 90% possess easy-plane …