Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …
Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups
Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …
strategies that is currently attracting tremendous attention with the aim to provide alternative …
Transition-metal-catalyzed direct addition of unactivated C–H bonds to polar unsaturated bonds
L Yang, H Huang - Chemical Reviews, 2015 - ACS Publications
Transition-metal-catalyzed nucleophilic addition of organometallic reagents to polar
unsaturated substrates is one of the most important and powerful bond-forming strategies …
unsaturated substrates is one of the most important and powerful bond-forming strategies …
Alkenylation of arenes and heteroarenes with alkynes
VP Boyarskiy, DS Ryabukhin, NA Bokach… - Chemical …, 2016 - ACS Publications
This review is focused on the analysis of current data on new methods of alkenylation of
arenes and heteroarenes with alkynes by transition metal catalyzed reactions …
arenes and heteroarenes with alkynes by transition metal catalyzed reactions …
Rhodium (III)-catalyzed intermolecular hydroarylation of alkynes
DJ Schipper, M Hutchinson… - Journal of the American …, 2010 - ACS Publications
The rhodium (III)-catalyzed hydroarylation of internal alkynes is described. Good yields are
obtained for a variety of alkynes, and excellent regioselectivity is observed for …
obtained for a variety of alkynes, and excellent regioselectivity is observed for …
Transition‐Metal‐Catalyzed π‐Bond‐Assisted C H Bond Functionalization: An Emerging Trend in Organic Synthesis
Transition‐metal‐catalyzed C H activation is considered to be an important tool in organic
synthesis and has been accepted and widely used by chemists because it is straightforward …
synthesis and has been accepted and widely used by chemists because it is straightforward …
Palladium-catalyzed annulation
RC Larock - Journal of organometallic chemistry, 1999 - Elsevier
The palladium-catalyzed annulation of cyclic and bicyclic alkenes, unsaturated
cyclopropanes and cyclobutanes, allenes, 1, 3-and 1, 4-dienes, as well as internal alkynes …
cyclopropanes and cyclobutanes, allenes, 1, 3-and 1, 4-dienes, as well as internal alkynes …
Polycyclic aromatic hydrocarbons via iron (iii)-catalyzed carbonyl–olefin metathesis
CC McAtee, PS Riehl, CS Schindler - Journal of the American …, 2017 - ACS Publications
Polycyclic aromatic hydrocarbons are important structural motifs in organic chemistry,
pharmaceutical chemistry, and materials science. The development of a new synthetic …
pharmaceutical chemistry, and materials science. The development of a new synthetic …
1, 3-Dien-5-ynes: versatile building blocks for the synthesis of carbo-and heterocycles
E Aguilar, R Sanz, MA Fernandez-Rodriguez… - Chemical …, 2016 - ACS Publications
1, 3-Dien-5-ynes have been extensively used as starting materials for the synthesis of a
wide number of different carbo-and heterocycles. The aim of this review is to give an …
wide number of different carbo-and heterocycles. The aim of this review is to give an …
Divergent C–H Annulation for Multifused N‐Heterocycles: Regio‐and Stereospecific Cyclizations of N‐Alkynylindoles
N‐Alkynylindoles were divergently cyclized for the synthesis of multifused N‐heterocycles.
An ortho‐aryl palladium species was added to the α position of an ynamine to generate (Z) …
An ortho‐aryl palladium species was added to the α position of an ynamine to generate (Z) …