Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

S Rej, A Das, N Chatani - Coordination Chemistry Reviews, 2021 - Elsevier
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Transition-metal-catalyzed direct addition of unactivated C–H bonds to polar unsaturated bonds

L Yang, H Huang - Chemical Reviews, 2015 - ACS Publications
Transition-metal-catalyzed nucleophilic addition of organometallic reagents to polar
unsaturated substrates is one of the most important and powerful bond-forming strategies …

Alkenylation of arenes and heteroarenes with alkynes

VP Boyarskiy, DS Ryabukhin, NA Bokach… - Chemical …, 2016 - ACS Publications
This review is focused on the analysis of current data on new methods of alkenylation of
arenes and heteroarenes with alkynes by transition metal catalyzed reactions …

Rhodium (III)-catalyzed intermolecular hydroarylation of alkynes

DJ Schipper, M Hutchinson… - Journal of the American …, 2010 - ACS Publications
The rhodium (III)-catalyzed hydroarylation of internal alkynes is described. Good yields are
obtained for a variety of alkynes, and excellent regioselectivity is observed for …

Transition‐Metal‐Catalyzed π‐Bond‐Assisted C H Bond Functionalization: An Emerging Trend in Organic Synthesis

P Gandeepan, CH Cheng - Chemistry–An Asian Journal, 2015 - Wiley Online Library
Transition‐metal‐catalyzed C H activation is considered to be an important tool in organic
synthesis and has been accepted and widely used by chemists because it is straightforward …

Palladium-catalyzed annulation

RC Larock - Journal of organometallic chemistry, 1999 - Elsevier
The palladium-catalyzed annulation of cyclic and bicyclic alkenes, unsaturated
cyclopropanes and cyclobutanes, allenes, 1, 3-and 1, 4-dienes, as well as internal alkynes …

Polycyclic aromatic hydrocarbons via iron (iii)-catalyzed carbonyl–olefin metathesis

CC McAtee, PS Riehl, CS Schindler - Journal of the American …, 2017 - ACS Publications
Polycyclic aromatic hydrocarbons are important structural motifs in organic chemistry,
pharmaceutical chemistry, and materials science. The development of a new synthetic …

1, 3-Dien-5-ynes: versatile building blocks for the synthesis of carbo-and heterocycles

E Aguilar, R Sanz, MA Fernandez-Rodriguez… - Chemical …, 2016 - ACS Publications
1, 3-Dien-5-ynes have been extensively used as starting materials for the synthesis of a
wide number of different carbo-and heterocycles. The aim of this review is to give an …

Divergent C–H Annulation for Multifused N‐Heterocycles: Regio‐and Stereospecific Cyclizations of N‐Alkynylindoles

K Alam, SW Hong, KH Oh, JK Park - Angewandte Chemie, 2017 - Wiley Online Library
N‐Alkynylindoles were divergently cyclized for the synthesis of multifused N‐heterocycles.
An ortho‐aryl palladium species was added to the α position of an ynamine to generate (Z) …