1. INTRODUCTION “All new is well-forgotten old”, the proverb goes. The current “fluorine
boom” 1 is news only to a novice in the field: the exceptional importance of fluorinated …

Chlorinated Solvents: Their Advantages, Disadvantages, and Alternatives in Organic and
Medicinal Chemistry | Chemical Reviews ACS ACS Publications C&EN CAS Find my …

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions
and have been applied in a range of contexts. This perspective attempts to aid the reader in …

The utility of copper-mediated cross-coupling reactions has been significantly increased by
the development of mild reaction conditions and the ability to employ catalytic amounts of …

Conspectus Cross-coupling reactions are powerful synthetic tools to construct diverse
chemical bonds often found in, for example, advanced materials and pharmaceuticals. Since …

Synthesis of biaryls via the Suzuki–Miyaura coupling (SMC) reaction using nitroarenes as
an electrophilic coupling partners is described. Mechanistic studies have revealed that the …

The unique chemical properties of aryl trifluoromethyl sulfides (ArSCF3) have been known
for over 60 years.[1] The capacity of SCF3 to act as a lipophilic electron-withdrawing group …

Functionalization of arenes is a topic of central importance in diverse fields ranging from
medicinal chemistry to materials science. Metal-catalyzed cross-coupling and nucleophilic …

A simple and general copper‐catalyzed method has been developed for transformations of
various functional groups ( I, N3, SO2R, OH, NH2, and NO2) on aromatic rings …

Nitroaromatic compounds represent one of the essential classes of molecules that are
widely used as feedstock for the synthesis of intermediates, the preparation of nitro‐derived …