Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications

N Corrigan, K Jung, G Moad, CJ Hawker… - Progress in Polymer …, 2020 - Elsevier
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …

Photoinduced organocatalyzed atom transfer radical polymerization (O-ATRP): precision polymer synthesis using organic photoredox catalysis

DA Corbin, GM Miyake - Chemical reviews, 2021 - ACS Publications
The development of photoinduced organocatalyzed atom transfer radical polymerization (O-
ATRP) has received considerable attention since its introduction in 2014. Expanding on …

Rational design of photocatalysts for controlled polymerization: effect of structures on photocatalytic activities

C Wu, N Corrigan, CH Lim, W Liu, G Miyake… - Chemical …, 2022 - ACS Publications
Over the past decade, the use of photocatalysts (PCs) in controlled polymerization has
brought new opportunities in sophisticated macromolecular synthesis. However, the …

Recent developments and future challenges in controlled radical polymerization: a 2020 update

K Parkatzidis, HS Wang, NP Truong, A Anastasaki - Chem, 2020 - cell.com
This perspective summarizes the latest exciting developments in controlled radical
polymerization during the last decade (2010–2020). Our focus is to critically highlight …

Toward green atom transfer radical polymerization: current status and future challenges

S Dworakowska, F Lorandi, A Gorczyński… - Advanced …, 2022 - Wiley Online Library
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …

Photocatalytic ATRP depolymerization: temporal control at low ppm of catalyst concentration

K Parkatzidis, NP Truong… - Journal of the …, 2023 - ACS Publications
A photocatalytic ATRP depolymerization is introduced that significantly suppresses the
reaction temperature from 170 to 100° C while enabling temporal regulation. In the presence …

Progress and perspectives beyond traditional RAFT polymerization

MD Nothling, Q Fu, A Reyhani… - Advanced …, 2020 - Wiley Online Library
The development of advanced materials based on well‐defined polymeric architectures is
proving to be a highly prosperous research direction across both industry and academia …

Ultrafast visible-light-induced ATRP in aqueous media with carbon quantum dots as the catalyst and its application for 3D printing

L Qiao, M Zhou, G Shi, Z Cui, X Zhang… - Journal of the …, 2022 - ACS Publications
Photoinduced atom transfer radical polymerization (ATRP) has been proved to be a versatile
technique for polymer network formation. However, the slow polymerization rates of typical …

Highly efficient dual photoredox/copper catalyzed atom transfer radical polymerization achieved through mechanism-driven photocatalyst design

W Jeon, Y Kwon, MS Kwon - Nature Communications, 2024 - nature.com
Atom transfer radical polymerization (ATRP) with dual photoredox/copper catalysis
combines the advantages of photo-ATRP and photoredox-mediated ATRP, utilizing visible …

Near‐Infrared Light‐Induced Reversible Deactivation Radical Polymerization: Expanding Frontiers in Photopolymerization

Z Wu, C Boyer - Advanced Science, 2023 - Wiley Online Library
Photoinduced reversible deactivation radical polymerization (photo‐RDRP) or photoinduced
controlled/living radical polymerization has emerged as a versatile and powerful technique …