[HTML][HTML] Bifunctional ligands in uranyl chemistry: metalloligands and zwitterions

P Thuéry, J Harrowfield - Coordination Chemistry Reviews, 2024 - Elsevier
Structural studies of uranyl ion complexes of metalloligands and zwitterions, ligand classes
with some degree of overlap, constitute a major contribution to more recent developments in …

Detection and identification of solids, surfaces, and solutions of uranium using vibrational spectroscopy

G Lu, AJ Haes, TZ Forbes - Coordination chemistry reviews, 2018 - Elsevier
The purpose of this review is to provide an overview of uranium speciation using vibrational
spectroscopy methods including Raman and IR. Uranium is a naturally occurring …

Highly-efficient uranium reduction, organic oxidation and electricity generation via a solar-driven wastewater resourceization system with a PANI/CF cathode

C **e, Q Zhang, Q Zeng, Q Zhang, Y Liu, G Tang… - Chemical Engineering …, 2024 - Elsevier
Co-existed organics bring great challenges for uranium recycling from water because of the
formation of obstinate complexes with uranyl ions (UO 2 2+), predominated species of …

Evaluating best practices in raman spectral analysis for uranium speciation and relative abundance in aqueous solutions

G Lu, TZ Forbes, AJ Haes - Analytical chemistry, 2016 - ACS Publications
Raman spectroscopy is emerging as a powerful tool for identifying hexavalent uranium
speciation in situ; however, there is no straightforward protocol for identifying uranyl species …

Cation templating and electronic structure effects in uranyl cage clusters probed by the isolation of peroxide-bridged uranyl dimers

J Qiu, B Vlaisavljevich, L Jouffret, K Nguyen… - Inorganic …, 2015 - ACS Publications
The self-assembly of uranyl peroxide polyhedra into a rich family of nanoscale cage clusters
is thought to be favored by cation templating effects and the pliability of the intrinsically bent …

Self‐Assembly of Uranyl–Peroxide Nanocapsules in Basic Peroxidic Environments

P Miró, B Vlaisavljevich, A Gil, PC Burns… - … A European Journal, 2016 - Wiley Online Library
A wide range of uranyl–peroxide nanocapsules have been synthesized using very simple
reactants in basic media; however, little is known about the process to form these species …

Synthesis, structure, luminescence and photocatalytic properties of an uranyl-2, 5-pyridinedicarboxylate coordination polymer

ZX Si, W Xu, YQ Zheng - Journal of Solid State Chemistry, 2016 - Elsevier
An uranium coordination polymer, namely [(UO 2 (pydc)(H 2 O)]· H 2 O (1)(H 2 pydc= 2, 5-
pyridinedicarboxylic acid), has been obtained by hydrothermal method and characterized by …

Synthesis, structural analysis, and supramolecular assembly of a series of in situ generated uranyl–peroxide complexes with functionalized 2, 2′-bipyridine and …

JA Ridenour, CL Cahill - New Journal of Chemistry, 2018 - pubs.rsc.org
The crystal structures of eight new binuclear peroxo-bridged uranyl (UO22+) complexes
containing chelating N-donating ligands (2, 2′-bipyridine [BPY] and 4, 4′-dibromo-2, 2 …

Time-resolved X-ray scattering and Raman spectroscopic studies of formation of a uranium-vanadium-phosphorus-peroxide cage cluster

J Qiu, M Dembowski, JES Szymanowski… - Inorganic …, 2016 - ACS Publications
Combining reactants in water under ambient conditions results in the assembly and
crystallization of 2.6 nm diameter cage clusters designated U48V6P48 within 3 weeks …

Occurrence of polyoxouranium motifs in uranyl organic networks constructed by using silicon-centered carboxylate linkers: structures, spectroscopy and computation

C Liu, XX Yang, S Niu, XY Yi, QJ Pan - Dalton Transactions, 2020 - pubs.rsc.org
Four novel polyoxouranium-based uranyl carboxylates have been constructed by using a
combination of three silicon-centered carboxylate ligands and polyoxouranium building …