The ion-intercalation-based rechargeable batteries are emerging as the most efficient
energy storage technology for electronic vehicles, grids, and portable devices. These …

Persistent and stable nitrogen‐centered organic radicals, including non‐heterocyclic/
heterocyclic nitrogen‐centered radicals and nitrogen‐centered radical complexes, have …

Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …

Photolysis of a platinum (II) azide complex in the presence of styrenes enables C═ C
double bond cleavage upon dissociative olefin imination to aldimido (PtII–N═ CHPh) and …

The redox series [Ir n (NH x)(PNP)](n= II–IV, x= 3–0; PNP= N (CHCHP t Bu2) 2) was
examined with respect to electron, proton, and hydrogen atom transfer steps. The …

Spin state is often regarded as the crucial valve to release the reactivity of energy‐related
catalysts, yet it is also challenging to precisely manipulate, especially for the active center …

Li‐rich oxide (LRO) cathodes that exhibit anionic redox activity can boost the energy density
of Li‐ion batteries. Oxygen redox in LROs can originate from the charge compensation of …

This review presents a comprehensive overview of the reactions of N2 within the
coordination sphere of transition metals of groups 6 to 9. Many of these metals mediate the …

The six-electron oxidation of two nitrides to N2 is a key step of ammonia synthesis and
decomposition reactions on surfaces. In molecular complexes, nitride coupling has been …

Several metalloenzymes, including [FeFe]-hydrogenase, employ cofactors wherein multiple
metal atoms work together with surrounding ligands that mediate heterolytic and concerted …