Cyclopropanation strategies in recent total syntheses

C Ebner, EM Carreira - Chemical reviews, 2017 - ACS Publications
Complex molecular architectures containing cyclopropanes present significant challenges
for any synthetic chemist. This review aims to highlight the strategic considerations for …

Propellanes—from a chemical curiosity to “explosive” materials and natural products

AM Dilmaç, E Spuling, A de Meijere… - Angewandte Chemie …, 2017 - Wiley Online Library
Propellanes are a unique class of compounds currently consisting of well over 10 000
representatives, all featuring two more or less inverted tetrahedral carbon atoms that are …

[КНИГА][B] Alkaloids: chemical and biological perspectives

SW Pelletier - 1983 - Springer
Alkaloids: chemical and biological perspectives Page 2 Alkaloids: Chemical and Biological
Perspectives Page 3 S. William Pelletier Editor Alkaloids: Chemical and Biological Perspectives …

Synthetic approaches towards alkaloids bearing α-tertiary amines

A Hager, N Vrielink, D Hager, J Lefranc… - Natural Product …, 2016 - pubs.rsc.org
Covering: up to August 2015 Alkaloids account for some of the most beautiful and
biologically active natural products. Although they are usually classified along biosynthetic …

Rhodium‐Catalyzed Asymmetric Cyclopropanation of Indoles with N‐Triftosylhydrazones

C He, W Song, D Wei, W Zhao, Q Yu… - Angewandte Chemie …, 2024 - Wiley Online Library
Herein we report a general rhodium‐catalyzed asymmetric intermolecular dearomative
cyclopropanation of indoles using trifluoromethyl N‐triftosylhydrazones as carbene …

Total synthesis of natural products using gold catalysis

S De, AK Dan, R Sahu, S Parida… - Chemistry–An Asian …, 2022 - Wiley Online Library
Gold catalysis is an extremely enthusiastic field of investigation in the catalysis area. The
development of alternative, highly inventive, precompetitive techniques based on gold …

Microwave-assisted synthesis of medium-sized heterocycles

A Sharma, P Appukkuttan… - Chemical …, 2012 - pubs.rsc.org
The development of new strategies for synthesis of medium-sized heterocycles has
remained a highly attractive but challenging proposition. In the last few years, the application …

Biologically Active Aspidofractinine, Rhazinilam, Akuammiline, and Vincorine Alkaloids from Kopsia

G Subramaniam, O Hiraku, M Hayashi… - Journal of Natural …, 2007 - ACS Publications
Eleven new indole alkaloids, in addition to the previously reported rhazinal (1), and 14 other
known alkaloids, were obtained from the Malayan Kopsia singapurensis, viz., kopsiloscines …

[HTML][HTML] Simmons–Smith cyclopropanation: A multifaceted synthetic protocol toward the synthesis of natural products and drugs: A review

R Munir, AF Zahoor, S Javed, B Parveen, A Mansha… - Molecules, 2023 - mdpi.com
Simmons–Smith cyclopropanation is a widely used reaction in organic synthesis for
stereospecific conversion of alkenes into cyclopropane. The utility of this reaction can be …

Alkaloids of the aspidospermine group

JE Saxton - The Alkaloids: Chemistry and Biology, 1998 - Elsevier
The alkaloids of the aspidospermine group have not been surveyed in this series since
Cordell's review in Volume 17 (1), which covered the area up to 1977. The present chapter …