Electrophotocatalysis: combining light and electricity to catalyze reactions
Visible-light photocatalysis and electrocatalysis are two powerful strategies for the promotion
of chemical reactions that have received tremendous attention in recent years. In contrast …
of chemical reactions that have received tremendous attention in recent years. In contrast …
Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?
F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …
with focus on how they contribute to the improvement of selectivity in heterogeneous …
Strategies to generate nitrogen-centered radicals that may rely on photoredox catalysis: development in reaction methodology and applications in organic synthesis
For more than 70 years, nitrogen-centered radicals have been recognized as potent
synthetic intermediates. This review is a survey designed for use by chemists engaged in …
synthetic intermediates. This review is a survey designed for use by chemists engaged in …
A perspective on late-stage aromatic C–H bond functionalization
L Zhang, T Ritter - Journal of the American Chemical Society, 2022 - ACS Publications
Late-stage functionalization of C–H bonds (C–H LSF) can provide a straightforward
approach to the efficient synthesis of functionalized complex molecules. However, C–H LSF …
approach to the efficient synthesis of functionalized complex molecules. However, C–H LSF …
Photoredox-catalyzed C–H functionalization reactions
N Holmberg-Douglas, DA Nicewicz - Chemical reviews, 2021 - ACS Publications
The fields of C–H functionalization and photoredox catalysis have garnered enormous
interest and utility in the past several decades. Many different scientific disciplines have …
interest and utility in the past several decades. Many different scientific disciplines have …
Powering the future: how can electrochemistry make a difference in organic synthesis?
The full control of redox events is of utmost importance to key aspects of molecular
synthesis. As a consequence, chemists have recognized the power of electrochemistry for …
synthesis. As a consequence, chemists have recognized the power of electrochemistry for …
Unraveling the structure and reactivity patterns of the indole radical cation in regioselective electrochemical oxidative annulations
X Liu, D Yang, Z Liu, Y Wang, Y Liu… - Journal of the …, 2023 - ACS Publications
Oxidation-induced strategy for inert chemical bond activation through highly active radical
cation intermediate has exhibited unique reactivity. Understanding the structure and …
cation intermediate has exhibited unique reactivity. Understanding the structure and …
Transformations of less-activated phenols and phenol derivatives via C–O cleavage
Employing phenols and phenol derivatives as electrophiles for cross-coupling reactions has
numerous advantages over commonly used aryl halides in terms of environmental …
numerous advantages over commonly used aryl halides in terms of environmental …
Recent advances in radical C–H activation/radical cross-coupling
Research and industrial interest in radical C–H activation/radical cross-coupling chemistry
has continuously grown over the past few decades. These reactions offer fascinating and …
has continuously grown over the past few decades. These reactions offer fascinating and …
Synthetic photoelectrochemistry
Photoredox catalysis (PRC) and synthetic organic electrochemistry (SOE) are often
considered competing technologies in organic synthesis. Their fusion has been largely …
considered competing technologies in organic synthesis. Their fusion has been largely …