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Local reaction environment in electrocatalysis
Beyond conventional electrocatalyst engineering, recent studies have unveiled the
effectiveness of manipulating the local reaction environment in enhancing the performance …
effectiveness of manipulating the local reaction environment in enhancing the performance …
Spatially and temporally understanding dynamic solid–electrolyte interfaces in carbon dioxide electroreduction
J Wang, HY Tan, MY Qi, JY Li, ZR Tang… - Chemical Society …, 2023 - pubs.rsc.org
The ubiquity of solid–liquid interfaces in nature and the significant role of their atomic-scale
structure in determining interfacial properties have led to intensive research. Particularly in …
structure in determining interfacial properties have led to intensive research. Particularly in …
Hydrogen bond network connectivity in the electric double layer dominates the kinetic pH effect in hydrogen electrocatalysis on Pt
The origin of the large kinetic pH effect in hydrogen electrocatalysis, that is, the
approximately two orders of magnitude decrease in reaction kinetics when moving from acid …
approximately two orders of magnitude decrease in reaction kinetics when moving from acid …
Construction of Co4 Atomic Clusters to Enable Fe−N4 Motifs with Highly Active and Durable Oxygen Reduction Performance
Fe− N− C catalysts with single‐atom Fe− N4 configurations are highly needed owing to the
high activity for oxygen reduction reaction (ORR). However, the limited intrinsic activity and …
high activity for oxygen reduction reaction (ORR). However, the limited intrinsic activity and …
Identification of the Highly Active Co–N4 Coordination Motif for Selective Oxygen Reduction to Hydrogen Peroxide
S Chen, T Luo, X Li, K Chen, J Fu, K Liu… - Journal of the …, 2022 - ACS Publications
Electrosynthesis of hydrogen peroxide (H2O2) through oxygen reduction reaction (ORR) is
an environment-friendly and sustainable route for obtaining a fundamental product in the …
an environment-friendly and sustainable route for obtaining a fundamental product in the …
Revealing the role of double-layer microenvironments in pH-dependent oxygen reduction activity over metal-nitrogen-carbon catalysts
A standing puzzle in electrochemistry is that why the metal-nitrogen-carbon catalysts
generally exhibit dramatic activity drop for oxygen reduction when traversing from alkaline to …
generally exhibit dramatic activity drop for oxygen reduction when traversing from alkaline to …
Polarization engineering of covalent triazine frameworks for highly efficient photosynthesis of hydrogen peroxide from molecular oxygen and water
Two‐electron oxygen photoreduction to hydrogen peroxide (H2O2) is seriously inhibited by
its sluggish charge kinetics. Herein, a polarization engineering strategy is demonstrated by …
its sluggish charge kinetics. Herein, a polarization engineering strategy is demonstrated by …
Probing electrolyte effects on cation-enhanced CO2 reduction on copper in acidic media
Tuning the properties of the electric double layer via cations is a recognized approach for
improving the efficiency of the CO2 reduction reaction (CO2RR). However, the mechanism …
improving the efficiency of the CO2 reduction reaction (CO2RR). However, the mechanism …
Theoretical modeling of electrochemical proton-coupled electron transfer
Proton-coupled electron transfer (PCET) plays an essential role in a wide range of
electrocatalytic processes. A vast array of theoretical and computational methods have been …
electrocatalytic processes. A vast array of theoretical and computational methods have been …
A polymeric hydrogel electrocatalyst for direct water oxidation
Metal-free electrocatalysts represent a main branch of active materials for oxygen evolution
reaction (OER), but they excessively rely on functionalized conjugated carbon materials …
reaction (OER), but they excessively rely on functionalized conjugated carbon materials …