Local reaction environment in electrocatalysis

C Chen, H **, P Wang, X Sun, M Jaroniec… - Chemical Society …, 2024 - pubs.rsc.org
Beyond conventional electrocatalyst engineering, recent studies have unveiled the
effectiveness of manipulating the local reaction environment in enhancing the performance …

Spatially and temporally understanding dynamic solid–electrolyte interfaces in carbon dioxide electroreduction

J Wang, HY Tan, MY Qi, JY Li, ZR Tang… - Chemical Society …, 2023 - pubs.rsc.org
The ubiquity of solid–liquid interfaces in nature and the significant role of their atomic-scale
structure in determining interfacial properties have led to intensive research. Particularly in …

Hydrogen bond network connectivity in the electric double layer dominates the kinetic pH effect in hydrogen electrocatalysis on Pt

P Li, Y Jiang, Y Hu, Y Men, Y Liu, W Cai, S Chen - Nature Catalysis, 2022 - nature.com
The origin of the large kinetic pH effect in hydrogen electrocatalysis, that is, the
approximately two orders of magnitude decrease in reaction kinetics when moving from acid …

Construction of Co4 Atomic Clusters to Enable Fe−N4 Motifs with Highly Active and Durable Oxygen Reduction Performance

A Han, W Sun, X Wan, D Cai, X Wang… - Angewandte Chemie …, 2023 - Wiley Online Library
Fe− N− C catalysts with single‐atom Fe− N4 configurations are highly needed owing to the
high activity for oxygen reduction reaction (ORR). However, the limited intrinsic activity and …

Identification of the Highly Active Co–N4 Coordination Motif for Selective Oxygen Reduction to Hydrogen Peroxide

S Chen, T Luo, X Li, K Chen, J Fu, K Liu… - Journal of the …, 2022 - ACS Publications
Electrosynthesis of hydrogen peroxide (H2O2) through oxygen reduction reaction (ORR) is
an environment-friendly and sustainable route for obtaining a fundamental product in the …

Revealing the role of double-layer microenvironments in pH-dependent oxygen reduction activity over metal-nitrogen-carbon catalysts

P Li, Y Jiao, Y Ruan, H Fei, Y Men, C Guo, Y Wu… - Nature …, 2023 - nature.com
A standing puzzle in electrochemistry is that why the metal-nitrogen-carbon catalysts
generally exhibit dramatic activity drop for oxygen reduction when traversing from alkaline to …

Polarization engineering of covalent triazine frameworks for highly efficient photosynthesis of hydrogen peroxide from molecular oxygen and water

C Wu, Z Teng, C Yang, F Chen, HB Yang… - Advanced …, 2022 - Wiley Online Library
Two‐electron oxygen photoreduction to hydrogen peroxide (H2O2) is seriously inhibited by
its sluggish charge kinetics. Herein, a polarization engineering strategy is demonstrated by …

Probing electrolyte effects on cation-enhanced CO2 reduction on copper in acidic media

ZM Zhang, T Wang, YC Cai, XY Li, JY Ye, Y Zhou… - Nature Catalysis, 2024 - nature.com
Tuning the properties of the electric double layer via cations is a recognized approach for
improving the efficiency of the CO2 reduction reaction (CO2RR). However, the mechanism …

Theoretical modeling of electrochemical proton-coupled electron transfer

RE Warburton, AV Soudackov… - Chemical …, 2022 - ACS Publications
Proton-coupled electron transfer (PCET) plays an essential role in a wide range of
electrocatalytic processes. A vast array of theoretical and computational methods have been …

A polymeric hydrogel electrocatalyst for direct water oxidation

Z Pei, H Tan, J Gu, L Lu, X Zeng, T Zhang… - Nature …, 2023 - nature.com
Metal-free electrocatalysts represent a main branch of active materials for oxygen evolution
reaction (OER), but they excessively rely on functionalized conjugated carbon materials …