Applications of metal selenium/tellurium compounds in materials science

VK Jain, G Kedarnath - Physical Sciences Reviews, 2019‏ - degruyter.com
Metal chalcogenides are technologically important materials. Physical, chemical, electrical
and mechanical properties of these materials can be fine-tuned by manipulating their shape …

Syntheses of Pd (II)/Pt (II) complexes with non-chelating 4-pyridylselenolate ligand ranging from mononuclear to macrocyclic structures and their utility as catalysts in …

KV Vivekananda, S Dey, A Wadawale… - Dalton …, 2013‏ - pubs.rsc.org
Treatment of Na2PdCl4 or [MCl2 (PhCN) 2] with bis (4-pyridyl) diselenide yielded an
insoluble product of composition [MCl2 (4, 4′-(C5H4N) 2Se2)] n (1). The reactions of …

Cooperation between Cis and Trans Influences in cis-PtII(PPh3)2 Complexes: Structural, Spectroscopic, and Computational Studies

L Rigamonti, A Forni, M Manassero… - Inorganic …, 2010‏ - ACS Publications
The relevance of cis and trans influences of some anionic ligands X and Y in cis-[PtX2
(PPh3) 2] and cis-[PtXY (PPh3) 2] complexes have been studied by the X-ray crystal …

Cis configured bis phosphine platinum (II) chalcogenolate complexes: Structures, NMR and computational studies

RS Chauhan, G Kedarnath, A Wadawale… - Journal of …, 2013‏ - Elsevier
Reactions of [PtCl2 (P∩ P)](P∩ P= dppm, dppe or dppp) with Pb (SMes) 2 and sodium
arylchalcogenolates yielded mononuclear complexes of the type, cis-[Pt (EAr) 2 (P∩ …

Structural and spectroscopic trends in mononuclear arylchalcogenolato-palladium (II) and-platinum (II) complexes: Crystal structures of [M (TeAr) 2 (dppe)]{M …

M Risto, EM Jahr, MS Hannu-Kuure… - Journal of …, 2007‏ - Elsevier
A series of mononuclear [M (EAr) 2 (dppe)][M= Pd, Pt; E= Se, Te; Ar= phenyl, 2-thienyl;
dppe= 1, 2-bis (diphenylphosphino) ethane] complexes has been prepared in good yields …

Reactivity of hemi-labile pyridyl and pyrimidyl derived chalcogen ligands towards group 10 metal phosphine precursors

RS Chauhan - New Journal of Chemistry, 2020‏ - pubs.rsc.org
A drive to understand the reactivity of hemi-labile organoselenide and telluride ligand
systems has made this area of research increasingly popular. For this purpose, various …

Mono-and disubstitution reactions of gyroscope like complexes derived from ClPtCl rotators within cage like dibridgehead diphosphine ligands

D Taher, AJ Nawara-Hultzsch, N Bhuvanesh… - Journal of …, 2016‏ - Elsevier
Reaction of the gyroscope like complex (trans-1c) and p-tolSeSiMe 3 (3.8 equiv, 85° C, melt)
gives the disubstitution product (trans-3c, 63%) and ClSiMe 3. Attempts to access a …

Iron Se-bonded mono-selenocarbonates CpFe (CO) 2SeCO2R: the first selenocarbonate complexes

M El-khateeb - Inorganica chimica acta, 2004‏ - Elsevier
The reactivity of the iron selenide complex (μ-Se)[CpFe (CO) 2] 2 toward chloroformates,
ROCOCl, has been studied and the products CpFe (CO) 2SeCO2R [R= Me (1), Et (2), iso-Bu …

cis Influence in trans-Pt (PPh 3) 2 complexes

L Rigamonti, C Manassero, M Rusconi… - Dalton …, 2009‏ - pubs.rsc.org
The cis influence of a series of anionic ligands X and Y has been evaluated through the
magnitude of the Pt–P coupling constants for compounds of formula trans-[PtXY (PPh3) 2] …

Trifluoromethylselenato (0) and trifluoromethyltellurato (0) complexes of platinum (II)

NV Kirij, W Tyrra, I Pantenburg, D Naumann… - Journal of …, 2006‏ - Elsevier
The series of cis/trans-trifluoromethylselenato complexes [Pt (SeCF3) 2− xClx (PPh3) 2](x=
0, 1) was identified by NMR spectroscopic methods. While in acetonitrile solution spectra are …