Relativistic pseudopotentials: their development and scope of applications

M Dolg, X Cao - Chemical reviews, 2012‏ - ACS Publications
The concept of valence and core electrons is familiar to every chemist and underlying, for
example, the ordering of the elements in the periodic table. For many qualitative …

Electron-correlated fragment-molecular-orbital calculations for biomolecular and nano systems

S Tanaka, Y Mochizuki, Y Komeiji, Y Okiyama… - Physical Chemistry …, 2014‏ - pubs.rsc.org
Recent developments in the fragment molecular orbital (FMO) method for theoretical
formulation, implementation, and application to nano and biomolecular systems are …

Room‐Temperature Phosphorescence Emitters Exhibiting Red to Near‐Infrared Emission Derived from Intermolecular Charge‐Transfer Triplet States of …

T Ono, K Kimura, M Ihara, Y Yamanaka… - … A European Journal, 2021‏ - Wiley Online Library
Room‐temperature phosphorescence (RTP) emitters have attracted significant attention.
However, purely organic RTP emitters in red to near‐infrared region have not been properly …

Cm 3+/Eu 3+ induced structural, mechanistic and functional implications for calmodulin

B Drobot, M Schmidt, Y Mochizuki, T Abe… - Physical Chemistry …, 2019‏ - pubs.rsc.org
Trivalent actinides and their lanthanide homologues are being scrutinized for their potential
health risk when ingested as a result of a range of industrial activities such as mining …

Core–shell excitation of isoxazole at the C, N, and O K-edges–an experimental NEXAFS and theoretical TD-DFT study

TJ Wasowicz, I Ljubić, A Kivimäki… - Physical Chemistry …, 2022‏ - pubs.rsc.org
The near-edge X-ray absorption fine structure (NEXAFS) spectra of the gas-phase isoxazole
molecule have been measured by collecting total ion yields at the C, N, and O K-edges. The …

Theoretical design of new macrocycles for nucleophilic fluorination with KF: thiourea-crown-ether is predicted to overcome [2.2. 2]-cryptand

EV Dalessandro, JR Pliego - Molecular Systems Design & …, 2020‏ - pubs.rsc.org
New macrocycles derived from dibenzo-18-crown-6 and molecules derived from
pentaethylene glycol were designed and investigated as catalysts for nucleophilic …

Modeling spin-forbidden monomer self-initiation reactions in spontaneous free-radical polymerization of acrylates and methacrylates

S Liu, S Srinivasan, J Tao, MC Grady… - The Journal of …, 2014‏ - ACS Publications
A spin-forbidden reaction is a reaction in which the total electronic spin-state changes. The
standard transition-state theory that assumes a reaction occurs on a single potential energy …

Fragment molecular orbital calculations on large scale systems containing heavy metal atom

T Ishikawa, Y Mochizuki, T Nakano, S Amari… - Chemical physics …, 2006‏ - Elsevier
We have realized a fully quantum mechanical treatment of large scale systems containing
heavy metal atom, by introducing the model core potential (MCP) technique into the …

The ABINIT-MP Program

Y Mochizuki, T Nakano, K Sakakura, Y Okiyama… - Recent Advances of the …, 2021‏ - Springer
We have been develo** the ABINIT-MP program system as an original code for the
fragment molecular orbital (FMO) calculations. ABINIT-MP has several unique features such …

An experimental NEXAFS and computational TDDFT and ΔDFT study of the gas-phase core excitation spectra of nitroxide free radical TEMPO and its analogues

I Ljubić, A Kivimäki, M Coreno - Physical Chemistry Chemical Physics, 2016‏ - pubs.rsc.org
Core-hole spectroscopy adds to the fundamental understanding of the electronic structure of
stable nitroxide free radicals thus paving way for a sensible design of new analogues with …